Výsledky vyhledávání - "Hans M. de Bruijn"

The Hydrogenation Problem in Cobalt‐based Catalytic Hydroaminomethylation

Autor: Elisabeth Bouwman, Célia Fonseca Guerra, F. Matthias Bickelhaupt, Hans M. de Bruijn

Publikováno v: ChemistrySelect, 5, 44, pp. 13981-13994
de Bruijn, H M, Fonseca Guerra, C, Bouwman, E & Bickelhaupt, F M 2020, ' The Hydrogenation Problem in Cobalt-based Catalytic Hydroaminomethylation ', ChemistrySelect, vol. 5, no. 44, pp. 13981-13994 . https://doi.org/10.1002/slct.202003294
Chemistry Select, 5(44), 13981-13994. WILEY-V C H VERLAG GMBH
ChemistrySelect, 5(44), 13981-13994. Wiley-Blackwell Publishing Ltd
ChemistrySelect, 5, 13981-13994

The hydroaminomethylation (HAM) reaction converts alkenes into N-alkylated amines and has been well studied for rhodium- and ruthenium-based catalytic systems. Cobalt-based catalytic systems are able to perform the essential hydroformylation reaction

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::9a641d2a1d0181477d027410279c0389
https://doi.org/10.1002/slct.202003294

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Application of the Ugi Multicomponent Reaction in the Synthesis of Reactivators of Nerve Agent Inhibited Acetylcholinesterase

Autor: Timo Wille, Marloes J.A. Joosen, Steven D. Klaassen, Florian Nachon, Hans M. de Bruijn, Duurt P. W. Alkema, Franz Worek, Martijn C. de Koning, Marco van Grol

Publikováno v: Journal of Medicinal Chemistry. 60:9376-9392

Recently, a new class of reactivators of chemical warfare agent inhibited acetylcholinesterase (AChE) with promising in vitro potential was developed by the covalent linkage of an oxime nucleophile and a peripheral site ligand. However, the complexit

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a0bed2d1210d334146c75c8106e8e844
https://doi.org/10.1021/acs.jmedchem.7b01083

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Palladium-Catalyzed Isomerization/(Cyclo)carbonylation of Pentenamides: a Mechanistic Study of the Chemo- and Regioselectivity

Autor: Bart Limburg, Elisabeth Bouwman, Hans M. de Bruijn, Yann Gloaguen, Eite Drent

Publikováno v: CHEMCATCHEM
CHEMCATCHEM, 9(15), 2961-2971

A new isomerizing ring‐closing amidocarbonylation reaction is reported using Pd catalysis with bulky diphosphane ligands. From terminal as well as internal pentenamide isomers (PAs), cyclic imides were obtained in good yield (92 %) with cationic Pd

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::acd9f20fb8bd06e70ff0dcc1d6829dbe
https://doi.org/10.1002/cctc.201700345

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Extremely bulky copper(i) complexes of [HB(3,5-{1-naphthyl}2pz)3]− and [HB(3,5-{2-naphthyl}2pz)3]− and their self-assembly on graphene

Autor: Tobias G. Brevé, Hans M. de Bruijn, Elisabeth Bouwman, Bob van Meijeren, Thomas F. van Dijkman, Maxime A. Siegler

Publikováno v: Dalton Transactions
Dalton Transactions, 46(19), 6433-6446

The synthesis and characterization, using NMR (1H and 13C), infrared spectroscopy, and X-ray crystallography, of the ethene and carbon monoxide copper(i) complexes of hydridotris(3,5-diphenylpyrazol-1-yl)borate ([TpPh2]-) and the two new ligands hydr

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::6cffee5c370cc05717b083f49614d6f8
https://doi.org/10.1039/c6dt04851j

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Factors Controlling the Diels–Alder Reactivity of Hetero-1,3-Butadienes

Autor: Hans M. de Bruijn, Trevor A. Hamlin, Dennis Svatunek, F. Matthias Bickelhaupt, Song Yu

Publikováno v: ChemistryOpen, 7(12), 995-1004. John Wiley and Sons Inc.
ChemistryOpen
Yu, S, de Bruijn, H M, Svatunek, D, Hamlin, T A & Bickelhaupt, F M 2018, ' Factors Controlling the Diels–Alder Reactivity of Hetero-1,3-Butadienes ', ChemistryOpen, vol. 7, no. 12, pp. 995-1004 . https://doi.org/10.1002/open.201800193

We have quantum chemically explored the Diels–Alder reactivities of a systematic series of hetero‐1,3‐butadienes with ethylene by using density functional theory at the BP86/TZ2P level. Activation strain analyses provided physical insight into

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::74e615b95d07ce6265871bb2a3428a8e
https://research.vu.nl/en/publications/1184ef69-3f13-4660-8bf9-5a0db230f0ff

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Bright Cyan Phosphorescence of a (Phosphane)copper(I) Complex of the Trihydridopyrazolylborate Ligand H 3 B(3,5‐Ph 2 Pz) –

Autor: Hans M. de Bruijn, Thomas F. van Dijkman, Maxime A. Siegler, Elisabeth Bouwman

Publikováno v: European Journal of Inorganic Chemistry. 2015:5387-5394

The ligand trihydrido(3,5-diphenylpyrazol-1-yl)borate([MpPh2]–) has been synthesized from 3,5-diphenylpyrazole and sodium borohydride in N,N-dimethylformamide. By using this ligand, three phosphane-stabilized copper(I) complexes [Cu(MpPh2)(L2)] [L2

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::946c38397caf81cd5fc0ef21d41fd465
https://doi.org/10.1002/ejic.201500812

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Extremely bulky copper(i) complexes of [HB(3,5-{1-naphthyl}

Autor: Thomas F, van Dijkman, Hans M, de Bruijn, Tobias G, Brevé, Bob, van Meijeren, Maxime A, Siegler, Elisabeth, Bouwman

Publikováno v: Dalton transactions (Cambridge, England : 2003). 46(19)

The synthesis and characterization, using NMR (

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=pmid________::1781fa75b6c8c2d6cc0312f61aa84262
https://pubmed.ncbi.nlm.nih.gov/28470290

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