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pro vyhledávání: '"Hana Nakajima"'
Publikováno v:
Chemical Communications. 57:2621-2624
An efficient method to synthesize diaryl sulfides with structural diversity is disclosed. Demethylative hydrothiolation of aryne intermediates generated from o-iodoaryl triflates with methylthio-substituted o-silylaryl triflates and further aryne rea
Autor:
Takamitsu Hosoya, Hana Nakajima, Keisuke Uchida, Takeshi Matsushita, Masakazu Kondo, Takahisa Yano, Suguru Yoshida
Publikováno v:
Chemistry Letters. 46:77-80
Reactions of arynes with sulfoximines are reported. The fate of these reactions depends on the substituents of the sulfoximines. S,S-Diarylsulfoximines reacted with arynes to selectively afford o-sulfinylanilines, whereas a simple N-arylation reactio