Zobrazeno 1 - 10
of 127
pro vyhledávání: '"Hakuai Inoue"'
Publikováno v:
Journal of Computer Chemistry, Japan. 2:127-134
The mechanism of the formose reaction catalyzed by thiazolium salt was investigated by MOPAC-PM3 semi-empirical molecular orbital (MO) method in order to elucidate the factor(s) stabilizing the reaction intermediates. We assumed that one factor was t
Publikováno v:
JOURNAL OF CHEMICAL ENGINEERING OF JAPAN. 35:564-568
We investigated the formose reaction using a zeolite impregnated with thiazolium catalyst. The zeolite catalyzed the formose reaction in an organic solvent and then the reaction rate was pseudo first order with respect to the formaldehyde concentrati
Publikováno v:
JOURNAL OF CHEMICAL ENGINEERING OF JAPAN. 34:553-557
We quantitatively studied the effects of counter anions and solvents on the catalytic activity of thiazolium due to the completion of the formose reaction using the highly active immobilized catalyst. The relation between counter anions and the catal
Publikováno v:
Journal of Applied Physics. 88:1900-1906
The dependence of the fluorescence lifetime of the 4S3/2 state of the Er3+ ion on the ErF3 concentration was measured in fluorozirconate glasses at room temperature. Energy transfer rates were calculated from optical parameters assuming that the Er3+
Publikováno v:
JOURNAL OF CHEMICAL ENGINEERING OF JAPAN. 33:793-796
Thiazolium ion catalyst was immobilized on a cation-exchange resin, and the formose reaction was carried out with the resin. As a result, the use of this resin turned out to be useful for the formose reaction in an organic solvent, similar to the fre
Publikováno v:
JOURNAL OF CHEMICAL ENGINEERING OF JAPAN. 33:894-897
In this study, we investigated about the effect of the unsteady diffusion on the reaction rate of an immobilized catalyst in a batch type reaction system. Analyzing the diffusion and reaction under the unsteady state, we showed that true kinetic info
Publikováno v:
Journal of Applied Physics. 86:6143-6149
Er3+ singly- and Er3+/Yb3+-codoped fluorozirconate glasses were prepared. The upconversion emission intensities of the Er3+ ion around both 550 and 660 nm were measured under 800 nm excitation. The absorption band of the Yb3+ ion is located around 98
Publikováno v:
JOURNAL OF CHEMICAL ENGINEERING OF JAPAN. 32:776-782
Thiamine is a primary catalyst of carbohydrate production from a simple chemical. As the best immobilization method, we succeeded in immobilization of thiamine on a cation exchange resin, and formaldehyde polymerization with the immobilized catalyst.
Publikováno v:
Journal of Applied Physics. 85:29-37
The upconversion emission intensities of Er3+ ion around 550 and 660 nm in fluorozirconate glasses were measured under 800 nm excitation. Though energy transfer processes played an important role in upconversion mechanism at high concentration of ErF
Publikováno v:
Journal of Non-Crystalline Solids. 222:272-281
Er-doped ZBLAN fluoride glasses and those containing chloride were prepared. The parameters of optical transitions were determined experimentally. By the introduction of chlorine as replacing NaF with NaCl up to 20 mol% NaCl, the Judd-Ofelt parameter