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Publikováno v:
Green Energy & Environment, Vol 9, Iss 1, Pp 104-113 (2024)
Implementing a new energy-saving electrochemical synthesis system with high commercial value is a strategy of the sustainable development for upgrading the bulk chemicals preparation technology in the future. Here, we report a multiple redox-mediated
Externí odkaz:
https://doaj.org/article/eb9c887259b3456ca8245e0d3a37e7fc
Publikováno v:
Angewandte Chemie (International ed. in English)My 5 top papers. 58(49)
"My worst nightmare is forgetting to prepare for a class. The most exciting thing about my research is discovering new reactions …" Find out more about Hai-Chao Xu in his Author Profile.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=pmid________::040bd7d45a5e9ad015747c44fbb8cf8d
https://pubmed.ncbi.nlm.nih.gov/31762199
https://pubmed.ncbi.nlm.nih.gov/31762199
Publikováno v:
Angewandte Chemie. 12/2/2019, Vol. 131 Issue 49, p17668-17668. 1p.
Publikováno v:
Nature Communications, Vol 13, Iss 1, Pp 1-7 (2022)
The direct hydroxylation of arene C–H bonds is a highly sought-after transformation but with little literature precedent. Herein the authors report a scalable electrochemical C–H hydroxylation of arenes in continuous flow for the synthesis of phe
Externí odkaz:
https://doaj.org/article/73bff5ac4d2748ceada9e7882fad6a63
Autor:
Hao Long, Chong Huang, Yun-Tao Zheng, Zhao-Yu Li, Liang-Hua Jie, Jinshuai Song, Shaobin Zhu, Hai-Chao Xu
Publikováno v:
Nature Communications, Vol 12, Iss 1, Pp 1-7 (2021)
Synthesis of aryl phosphorus compounds with electron-withdrawing substituents on the arene is difficult to do simply. Here the authors show a method to form aryl carbon-phosphorus bonds through electrochemistry, without requiring any catalyst or exte
Externí odkaz:
https://doaj.org/article/040c115128194231a97296b5b1a1ae00
Autor:
Bin Guo, Hai-Chao Xu
Publikováno v:
Beilstein Journal of Organic Chemistry, Vol 17, Iss 1, Pp 2650-2656 (2021)
Electrocatalytic dehydrogenative C(sp3)–H/C(sp)–H cross-coupling of tetrahydroisoquinolines with terminal alkynes has been achieved in a continuous-flow microreactor through 2,2,6,6-tetramethylpiperidine 1-oxyl (TEMPO)/copper relay catalysis. The
Externí odkaz:
https://doaj.org/article/3e4d4f616e3142d0984511eddcde6401
Publikováno v:
Nature Communications, Vol 12, Iss 1, Pp 1-9 (2021)
Oxidative allylic C–H functionalizations minimise the need for functional group activation and generate alkenyl-substituted products amenable to further chemical modifications. Here the authors report an oxidant-free, electrocatalytic approach to a
Externí odkaz:
https://doaj.org/article/f805f67bc6b2459a8fe06a15095cebe7
Autor:
Na Chen, Hai-Chao Xu
Publikováno v:
Green Synthesis and Catalysis, Vol 2, Iss 2, Pp 165-178 (2021)
There is a resurgence of interests in organic electrochemistry, which is generally accepted as a green synthetic tool. In this context, many electrochemical methods have been developed in the past decade to access various nitrogen-centered radicals (
Externí odkaz:
https://doaj.org/article/a19b2cbe44b34fc9afaa5c166b8ed838
Autor:
Peng Xiong, Huai-Bo Zhao, Xue-Ting Fan, Liang-Hua Jie, Hao Long, Pin Xu, Zhan-Jiang Liu, Zheng-Jian Wu, Jun Cheng, Hai-Chao Xu
Publikováno v:
Nature Communications, Vol 11, Iss 1, Pp 1-8 (2020)
Benzylic oxygenation of methylarenes is a direct but challenging method for aldehyde synthesis from simple starting materials. Here, the authors show an electrochemical, site-selective method for the oxidation of methyl benzoheterocycles to aromatic
Externí odkaz:
https://doaj.org/article/9879b00c89c44d29b40cc1f9ba7d8744