Zobrazeno 1 - 10
of 85
pro vyhledávání: '"H.J. de Liefde Meijer"'
Autor:
F. W. Siegert, H.J. de Liefde Meijer
Publikováno v:
Recueil des Travaux Chimiques des Pays-Bas. 89:764-768
The preparation of complexes of the type (π-C5H5)2VR2 has been attempted by reaction of one mole of vanadocene dichloride with two moles of an organo-metallic reagent RM (RM = C6H5Na and C6F5Li); these reactions result in the formation of complexes
Publikováno v:
Recueil des Travaux Chimiques des Pays-Bas. 85:1025-1038
Experiments are described aiming at a simplification of the catalyst system originally consisting of a mixture of tetraphenyltin, aluminium bromide and vanadium tetrachloride (or vanadium oxytrichloride). It is shown that tetraphenyltin merely acts a
Publikováno v:
Recueil des Travaux Chimiques des Pays-Bas. 85:1007-1017
The polymerization of ethylene with Ziegler-type catalysts containing mono- and bis-cyclopentadienylvanadium compounds as constituents has been studied. The activities of these catalyst mixtures have been compared with those of two known highly activ
Publikováno v:
Recueil des Travaux Chimiques des Pays-Bas. 84:1418-1426
Cp2V and Cp2VR (Cp = πC5H5, R = alkyl or aryl) were found to react with atmospheric oxygen to give a product with the empirical formula C10H12O5V2. Evidence was obtained that in the oxidation product cyclopentadienyl rings π‐bonded to the vana
Autor:
H.J. de Liefde Meijer, J.H. Teuben
Publikováno v:
Recueil des Travaux Chimiques des Pays-Bas. 90:360-363
Autor:
H.J. de Liefde Meijer, F. W. Siegert
Publikováno v:
Recueil des Travaux Chimiques des Pays-Bas. 87:1445-1446
Publikováno v:
Journal of Organometallic Chemistry, 97(1), 73-77. Elsevier Science
He(I) photoelectron spectra of the compounds (C5H5)M(C7H7) (M = Zr, Nb, Mo) are reported. The results are compared with those for the corresponding 3d transition metal compounds and discussed in terms of qualitative MO considerations.
Publikováno v:
Journal of Organometallic Chemistry, 81(3), 379-384. Elsevier Science
The synthesis properties of the compounds (C 5 H 5 )M(C 7 H 7 ) with M = Zr and Nb are described. The Zr compounds is diamagnetic; its PMR spectrum shows two singlets with intensities in the ratio of 7/5; the niobium compound has one unpaired electro
Publikováno v:
Journal of Organometallic Chemistry, 74(2), 245-253. Elsevier Science
The synthesis and the properties of the complexes Cp2TaCl2, Cp2M(allyl), Cp2M(1-methylallyl) and Cp2M(2-methylallyl) with M Nb, Ta are described. The complex Cp2TaCl2 has one unpaired electron per tantalum atom, while the allyl complexes are diam
Autor:
J. L. de Boer, H.O. Van Oven, F. Jellinek, H.J. de Liefde Meijer, H. R. van der Wal, F. Overzet
Publikováno v:
Journal of Organometallic Chemistry, 92(3), 329-340. Elsevier Science
The syntheses and the results of mass spectrometry and infrared spectroscopy are reported of cyclooctatetraenetitanium chloride and its adducts with the donor molecules THF, diethylamine, pyrrolidine and pyridine. Single-crystal X-ray diffraction sho