Výsledky vyhledávání

Fluorination of tetrafluorobenzenes C6HF4R with XeF2

Autor: H.J. Frohn, V.V. Bardin, L.N. Shchegoleva

Publikováno v: Journal of Fluorine Chemistry. 77:153-159

Replacement of hydrogen by fluorine and addition of fluorine atoms to the aromatic ring were found in the reaction of XeF2 with 1,2,3,4,5-tetrafluorobenzene (RH, F, Br, NO2) or 1-R-2,3,4,6-tetrafluorobenzene (RH, CF3) in HF or CH2Cl2BF3·OEt

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::56ca1620de9748fd52254a4d9a9f7eab
https://doi.org/10.1016/0022-1139(96)03401-x

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Preparation, NMR spectra and reactivity of pentafluorophenyltetrafluorosilicates M+ [C6F5SiF4]−

Autor: V.V. Bardin, H.J. Frohn

Publikováno v: Journal of Organometallic Chemistry. 501:155-159

Pentafluorophenyltetrafluorosilicates M + [C 6 F 5 SiF 4 ] − were obtained from pentafluorophenyltrifluorosilane C 6 F 5 SiF 3 and ionic fluorides MF (M  K, Cs, Me 4 N) in anhydrous MeCN or diglyme. The reactivity of M + [C 6 F 5 SiF 4 ] − tow

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::4deceaacbe185bf1c38b2474152fc64a
https://doi.org/10.1016/0022-328x(95)05616-w

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Fluorination of C6F5MX3 compounds (MSi, Ge; XF, Cl, Br, Alk) with xenon difluoride and XeF+ Y- salts

Autor: V.V. Bardin, H.J. Frohn

Publikováno v: Journal of Fluorine Chemistry. 60:141-151

Compounds of the formula C 6 F 5 MX 3 (MSi, Ge; XCl, Br) react with XeF 2 , exchangingchlorine (bromine) atoms for fluorine. Interaction of C 6 F 5 MX 3 (XF, Alk) with XeF 2 inthe presence of BF 3 ·OEt 2 or with XeF + NbF 6 - proceeds by th

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::01f63e88a4cddbdc79856b52ce7a7365
https://doi.org/10.1016/s0022-1139(00)80028-7

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ChemInform Abstract: Reactions of Pentafluorophenylxenon(II) Hexafluoroarsenate (C6F5Xe)+( AsF6)- with Aromatic Compounds

Autor: V.V. Bardin, H.J. Frohn, A. Klose

Publikováno v: ChemInform. 25

Pentafluorophenylxenon(II) hexafluoroarsenate [C 6 F 5 Xe] + [AsF 6 ] − reacts (MeCN, 20 °C) with aromatic compounds C 6 H 5 X (X = CH 3 , F, CF 3 , NO 2 and CN), yielding isomeric mixtures of polyfluorinated biphenyls XC 6 H 4 C 6 F 5 . When X =

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::9531ebf08eae29accc117bf08bdc165c
https://doi.org/10.1002/chin.199413109

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Beiträge zur chemie des brompentafluorids 2. Teil: phenyl-, fluorphenyl- und trifluormethylphenylbrom(v)tetrafluoride

Autor: W. Breuer, H.J. Frohn

Publikováno v: Journal of Fluorine Chemistry. 47:301-315

Arylbromine(V)tetrafluorides X-C6H4-BrF4 (X = o-F, m-F, p-F, o-CF3, m-CF3, p-CF3, and H) can be prepared by fluorine-aryl - substitution on BrF5 in organic solvents. The influence of different aryl-transfer - reagents, of substituents in the aryl- gr

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::87535ca1bf12d0a530a2d553b833a9be
https://doi.org/10.1016/s0022-1139(00)82381-7

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Reactions of pentafluorophenylxenon(II) hexafluoroarsenate [C6F5Xe]+[AsF6]− with aromatic compounds

Autor: H.J. Frohn, V.V. Bardin, A. Klose

Publikováno v: Journal of Fluorine Chemistry. 58:320

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::c808cf22d6da82647022aaaf4f8f4c3c
https://doi.org/10.1016/s0022-1139(00)80781-2

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New pentafluorophenyliodine(III) and (V) compounds

Autor: H.J. Frohn, A. Priwitzer, S. Görg

Publikováno v: Journal of Fluorine Chemistry. 58:320

The synthesis of (C6F5)2IF and (C6F5)3I was achieved by using C6F5IF2 as a synthon in fluorine aryl substitution. The new compounds which are stable at room temperature were analytically and spectroscopically characterized. Initial findings of their

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::27458e64299a31eb122917abda2eb083
https://doi.org/10.1016/s0022-1139(00)80782-4

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[C6F5Xe]+ as potential source of the electrophilic [C6F5] radical

Autor: H.J. Frohn, A. Klose

Publikováno v: Journal of Fluorine Chemistry. 58:274

Thermal decomposition of [C 6 F 5 Xe] + salts with complex fluoroanions can proceed in two different ways: a crypto-ionic and/or a radical path, depending on temperature and solvent. The intermediate formation of long-lived radical pairs could be est

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::8f538a1aa2f64aad0f9e716a99937853
https://doi.org/10.1016/s0022-1139(00)80729-0

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The preparation of [mCF3C6H4Xe]+ and other monosubstituted phenylxenon(II)-cations

Autor: Chr. Rossbach, St. Jakobs, H.J. Frohn

Publikováno v: Journal of Fluorine Chemistry. 54:8

After successful preparation and structural characterization of [C 6 F 5 Xe] + -salts we report on the synthesis of monosubstituted phenylxenon cations now. For example. [mCF 3 C 6 H 4 Xe] + is a typical species and allows to investigate the influ

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::fe36995d7fcd7e7b83efa017ac83ee14
https://doi.org/10.1016/s0022-1139(00)83518-6

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New organoiodine(III)-fluorine compounds

Autor: A. Priwitzer, H.J. Frohn

Publikováno v: Journal of Fluorine Chemistry. 54:322

Besides IF 3 no binary iodine(III) oxide or ternary iodine(III) fluoride oxide is known. Now we report on the preparation of an organoiodine(III) fluoride oxide: C 6 F 5 I(F)OI(F)C 6 F 5 ( I ). I is prepared by well-aimed fluorine-oxygen — metathes

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::bb8dac24be04edfca7020c7b6bb0181e
https://doi.org/10.1016/s0022-1139(00)83831-2

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