Zobrazeno 1 - 10 of 77 pro vyhledávání: '"H.C Volger"'
1
Organic halide-ethylene growth reaction catalyzed by ruthenium complexes
Autor: J.L. Van Winkle, H.C. Volger, Lynn Henry Slaugh, Eugene F. Magoon, W.W. Spooncer
Publikováno v: Journal of Organometallic Chemistry. 99:135-144
Ru(CO) 3 (PPh 3 ) 2 and a variety of other zero-valent ruthenium complexes promote the reaction of iodoalkanes with ethylene to produce higher molecular weight 1-iodoalkanes. The chemistry is best explained by the intermediacy of alkyl radicals gener
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::3a4528db25934cf5217353ffdbbebd84
https://doi.org/10.1016/s0022-328x(00)86370-6
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2
Boron hydride reduction of transition metal—acetyl complexes
Autor: Christopher Masters, H.C. Volger, J. A. Van Doorn
Publikováno v: Journal of Organometallic Chemistry. 105:245-254
Acetyl complexes of iron(II) and ruthenium(II) of the type (π-C 5 H 5 )(CO)LM(COCH 3 ), where L = PPh 3 , P(OPh) 3 , P(cyclohexyl) 3 , PMe 2 Ph or CO for M = Fe, and PPh 3 for M = Ru, are rapidly reduced to the corresponding ethyl complexes by BH 3
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::f5a386aedaedc1687b824b8cc4162ddb
https://doi.org/10.1016/s0022-328x(00)88962-7
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4
π-allylic complexes of rhodium(III) and platinum(II) IV. Chemical reactivity of π-allylic platinum complexes
Autor: H.C. Volger, K. Vrieze
Publikováno v: Journal of Organometallic Chemistry. 13:495-503
The reactions of {[C6H5)3P]2Pt(π-C3H5)}+Cl− and of the π-1,1-dimethylallylic analogue with hydrogen, hydrogen chloride, sulfur dioxide, carbon monoxide, ethene and 1,3-butadiene were studied. With hydrogen and hydrogen chloride the corresponding
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::4d31297d81d2921d8891cd782093c3d9
https://doi.org/10.1016/s0022-328x(00)82777-1
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5
Complexes of allenes with platinum (II) and rhodium (I)
Autor: K. Vrieze, H.C. Volger, A.P. Praat
Publikováno v: Journal of Organometallic Chemistry. 21:467-475
The π-allene-metal linkage in compounds of tetramethylallene (TMA) and 1,1-dimethylallene (1,1-DMA) with platinum (II) and rhodium (I) has been investigated. The compounds were: the dimers [(TMA)PtCl2]2 and [(1,1-DMA)PtCl2]2, prepared by reaction of
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::2a87110107087c3b56116936c35becbc
https://doi.org/10.1016/s0022-328x(00)83648-7
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6
Mechanistic aspects of the carbonylation of Allyl chloride catalysed by π-allylic palladium complexes
Autor: H.C. Volger, J. W. F. M. Lemmers, P.W.N.M. van Leeuwen, A.P. Praat, K. Vrieze
Publikováno v: Inorganica Chimica Acta. 4:435-440
The mechanism of the carbonylation of allyl chloride to vinyl acetyl chloride catalysed by π-allylic palladium complexes has been investigated in some detail. An earlier observation that on addition of group V donor ligands (L) the reaction rate is
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::5553c207d1d2a225bc718b0792abd600
https://doi.org/10.1016/s0020-1693(00)93322-x
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8
π-allylic complexes or rhodium(III) and platinum(II) III. Chemical reactivity of π-allylic rhodium(III) complexes
Autor: H.C. Volger, K. Vrieze
Publikováno v: Journal of Organometallic Chemistry. 13:479-493
The reactions of L2Rh(π-C3H4R)Cl2 [L = (C6H5)3P, (C6H5)3As or (C6H5)3Sb and R = H or CH3] with sulfur dioxide, ethene and carbon monoxide were studied. Sulfur dioxide gives rise to the formation of a σ-allylic rhodium-sulfur dioxide complex. With c
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::be9a5912fa1b068f9501582fc84d8b80
https://doi.org/10.1016/s0022-328x(00)82776-x
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9
Nuclear magnetic resonance studies in coordination Chemistry VI. Kinetic studies of reactions involving [(1,5-Cyclooctadiene)IrCl]2 and triphenylarsine or triphenylphosphine
Autor: H.C. Volger, K. Vrieze, A.P. Praat
Publikováno v: Journal of Organometallic Chemistry. 14:429-440
NMR kinetic investigations have been carried out on systems containing the 1,5-cyclooctadiene complexes (COD)IrCl(L) as such or in combination with [(COD)IrCl]2 or L(L=AsPh3 or PPh3). The results for mixtures of (COD)IrCl(L) and L indicate that at lo
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::e13bfc273d5ad84f7f6efe27fae4e37b
https://doi.org/10.1016/s0022-328x(00)87684-6
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10
The stereospecific addition of dienes to palladium chloride
Autor: H.C. Volger, Arjan P. Kouwenhoven, P.W.N.M. van Leeuwen, J. Lukas
Publikováno v: Journal of Organometallic Chemistry. 47:153-163
Using 2,4-hexadiene as a model compound we have shown that dienes add to palladium chloride in a stereospecific way. The three diene isomers react to give a pair of epimeric π-allylpalladium diastereomers, one of which is formed from the cis,trans-d
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::1bf15572128ac18fb613579156269aaa
https://doi.org/10.1016/s0022-328x(00)92851-1
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