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Publikováno v:
International Journal for Radiation Physics and Chemistry. 8:477-481
In this paper we describe the characteristics of two photodiodes which make them very useful for pulse radiolysis studies. These detectors are the EG & G SHS-100 Si photodiode and the Barnes room temperature A-100 InAs photodiode. The former has a li
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::fb6c3c3cc56cc0f3bab1ad60d80d38ac
https://doi.org/10.1016/0020-7055(76)90011-5
https://doi.org/10.1016/0020-7055(76)90011-5
Publikováno v:
Chemical Physics Letters. 49:459-462
Electrons produced by pulse radiolysis in glasses of 32 mole % methanol in MTHF at 109 K exhibit a spectral blue-shift from 0.1–14 μs indicating predominant initial solvation by the more abundant MTHF molecules converting to final solvation by the
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::6569415eea9459b34e870cd0c2fc07f7
https://doi.org/10.1016/0009-2614(77)87014-0
https://doi.org/10.1016/0009-2614(77)87014-0
Publikováno v:
The Journal of Chemical Physics. 62:2474-2476
The initial (?200 nsec) spectra of the trapped electron are similar in C2H5OH, C2H5OD, C2D5OH, and C2D5OD glasses at 76 K with λmax ∼1300 nm. The kinetics of the spectral shifts to the stable values of λmax near 540 nm are similar for C2H5OH and
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::03e3ac8053c55e7189caa46865217df1
https://doi.org/10.1063/1.430726
https://doi.org/10.1063/1.430726
Publikováno v:
Chemical Physics Letters. 10:481-483
A broad absorption spectrum with λ max ⩾ 2000 nm has been observed in pulse-irradiated liquid propane at low temperatures, and assigned to the solvated electron. The electron decays by geminate recombination with an initial half-life of ⩽ 95 nse
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::ae3878564a7c846f9bbab5928119b82d
https://doi.org/10.1016/0009-2614(71)80339-1
https://doi.org/10.1016/0009-2614(71)80339-1
An IR absorption band with a maximum beyond 2400 nm has been found and assigned to the electron in the following systems irradiated at 76 K: crystalline D 2 O, and D 2 O glasses of ethylene glycol, MgCl 2 and LiCl. The band is tentatively attributed
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::628d76c9edf3232a44e003a910af83c9
https://doi.org/10.1016/0009-2614(75)85234-1
https://doi.org/10.1016/0009-2614(75)85234-1
In the pulse radiolysis of ethylene glycol-D 2 O glass at 6 K, G (e - IR ) ⋍ 4.9 and G (e - vis )⋍0.3; by contrast pulse radiolysis of pure ethylene glycol glass at 6 K gives very little IR absorption. The effect of previous irradiation at 6 or 7
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::4fbf3b3335ab7ed0fef42fb9be1d9ad3
https://doi.org/10.1016/0146-5724(81)90038-8
https://doi.org/10.1016/0146-5724(81)90038-8
The optical absorption spectrum obtained by pulse radiolysis of pure liquid dimethylsulphoxide includes a broad intense band in the near IR with λmax ⩾ 1500 nm. This band is assigned to solvated electrons with a half-life of 15 ± 2 nsec. The λma
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b12883a131e031dd8989b86b0958f281
https://nrc-publications.canada.ca/eng/view/object/?id=8e186763-5f84-4ae5-b317-4b8f1f94f82d
https://nrc-publications.canada.ca/eng/view/object/?id=8e186763-5f84-4ae5-b317-4b8f1f94f82d