Zobrazeno 1 - 10
of 98
pro vyhledávání: '"H. Slebocka-Tilk"'
Publikováno v:
Journal of the American Chemical Society. 125:1851-1858
An NMR study of the rates of hydroxide-promoted hydrolysis of formamide in aqueous media of varying mole fraction D(2)O (n) was performed at [LO(-)] = 1.42 M, T = 25 degrees C, to shed light on whether the mechanism involves a nucleophilic attack of
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::92293a2cdb4a4323a124307a631ba19f
https://doi.org/10.1021/ja021055z
https://doi.org/10.1021/ja021055z
Publikováno v:
Canadian Journal of Chemistry. 80:1343-1350
A study of the hydrolysis of formamide is reported with the aims of isolating the water reaction for hydrolysis from the acid and base hydrolysis terms and determining the solvent deuterium kinetic isotope effect (dkie) on base-catalyzed hydrolysis.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::451933e8399b5a37fb333910748ba43a
https://doi.org/10.1139/v02-166
https://doi.org/10.1139/v02-166
Publikováno v:
Canadian Journal of Chemistry. 77:1577-1588
The hydrolysis of p-nitrophenyldiphenyl phosphate (PNPDPP, 7) catalyzed by N-dodecylaminoethanol (6a), N-tetradecylaminoethanol (6b), N-methyl-N-tetradecylaminoethanol (6c), and N-hexadecylaminoethanol (6d) was investigated at 25°C at various pH val
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::4d8b8badb7d4da792e1d420d400965a4
https://doi.org/10.1139/v99-161
https://doi.org/10.1139/v99-161
Autor:
A. Neverov, J. L. Gainsforth, S. Motallebi, R. S. Brown, O. Donini, Mariusz Klobukowski, H. Slebocka-Tilk
Publikováno v:
Journal of the American Chemical Society. 120:2578-2585
The electrophilic addition of Br2 to specifically deuterated cyclohexenes (1−5) was studied methanol (MeOH) by stopped-flow kinetics in order to determine a deuterium kinetic isotope effect (DKIE) ...
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::e669742de0480cd58ad9e2169aabb9aa
https://doi.org/10.1021/ja971145h
https://doi.org/10.1021/ja971145h
Autor:
H. Slebocka-Tilk, Christopher G. Rescorla, Salma Shirin, Robert S. Brown, and Andrew J. Bennet
Publikováno v:
Journal of the American Chemical Society. 119:10969-10975
The water catalyzed hydrolyses of p-nitrotrifluoroacetanilide (3) and trifluoroacetanilide (8) were studied at various pH's and temperatures. The activation parameters for the water reactions of 3 and 8 are: ΔH⧧ = 14.4 ± 0.6 and 11.7 ± 0.3 kcal/
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::3c02f240c320f9ac415a9424aa6af003
https://doi.org/10.1021/ja971463g
https://doi.org/10.1021/ja971463g
Autor:
Robert S. Brown, H. Slebocka-Tilk
Publikováno v:
The Journal of Organic Chemistry. 61:8079-8082
The acid-catalyzed hydration of anti-sesquinorbornene (1) has been studied at 25 degrees C in 20% DME/H(2)O from 0.001 M < [HC1] < 0.05 M. The second-order rate constant for hydration is 5.35 +/- 0.07 M(-)(1) s(-)(1) which can be compared with a valu
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::817d15c23e1ffddac8c7a11d8989a69e
https://doi.org/10.1021/jo9611677
https://doi.org/10.1021/jo9611677
Publikováno v:
The Journal of Organic Chemistry. 61:3458-3466
The kinetics and products of addition of Br2 in MeOH to anti-sesquinorbornene (1) have been studied at 25 °C in the presence of varying [LiBr]. The products consist of ∼10% cis dibromide and 90% cis methoxy bromide, the amounts of these being inde
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::43b5b603ba8bacb7b7706013b1f961bd
https://doi.org/10.1021/jo951746w
https://doi.org/10.1021/jo951746w
Publikováno v:
Journal of the American Chemical Society. 117:8769-8776
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::46b4950982f951fe81b7b8e59f8156cf
https://doi.org/10.1021/ja00139a009
https://doi.org/10.1021/ja00139a009
Autor:
G. H. M. Aarts, Roberto Ambrosetti, H. Slebocka-Tilk, Andrew J. Bennet, Robert S. Brown, Roberto Bianchini, Donata Ines Maria Catalano, Cinzia Chiappe, Giuseppe Bellucci
Publikováno v:
The Journal of Organic Chemistry. 58:3401-3406
A dynamic 1 H NMR study of the adamantylideneadamantane (Ad=Ad)/Br 2 system has been undertaken in d 4 -1,2-dichloroethane as a function of excess [Br 2 ] and temperature. Bromine site exchange rate constants (k NMR ) nvere determined by line shape a
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::f5a82541cf850155360385322a9c8dc8
https://doi.org/10.1021/jo00064a032
https://doi.org/10.1021/jo00064a032
Publikováno v:
The Journal of Organic Chemistry. 58:2122-2127
The trans-2-bromotriflate of cycloherane (4) has been solvolyzed at ambient temperatures in HOAc and MeOH containing varying [Br - ] and in the presence of 0.5 M of a scavenger olefin, cyclopentene. The kinetics of solvolysis of 4 have been determine
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::75ddc9275bba4bf2d4ccfdf777901f6a
https://doi.org/10.1021/jo00060a031
https://doi.org/10.1021/jo00060a031