Zobrazeno 1 - 10
of 16
pro vyhledávání: '"H. Martin Gillis"'
Autor:
Athanasios Karagiannis, Garrison E. Beye, Vishal Jheengut, Fabiola Becerril-Jiménez, Dale E. Ward, H. Martin Gillis
Publikováno v:
Synlett. 2011:508-512
Aldol reactions of racemic enolizable dioxolan-protected α-substituted-β-ketoaldehydes with representative achiral ketones catalyzed by proline or 5-(2-pyrrolidine-2-yl)-1H-tetrazole in wet DMSO proceed with dynamic kinetic resolution (or via DYKAT
Publikováno v:
Synlett. 2009:112-116
Sulfenyl groups are attracting interest as masking/protectinggroups for pyrroles. A facile one-step synthesis of sulfenyl pyrroles,involving the reaction of pyrroles with N-(aryl-and alkyl-thio)phthalimides in the presence of MgBr 2 ,is reported and
Publikováno v:
Journal of Porphyrins and Phthalocyanines. 12:918-931
The Thompson group aims to further the chemistry of pyrroles, dipyrrins and prodigiosenes. This micro-review discusses each of these research areas in turn, focussing on our achievements thus far.
Publikováno v:
Canadian Journal of Chemistry. 86:676-681
The asymmetric oxidation of prochiral 2-(arylsulfenyl)pyrroles has been investigated. A marked electronic effect within the substrate significantly influenced the degree of enantioselectivity obtained, with very high enantio selectivity being obtaine
Publikováno v:
ChemInform. 40
The Thompson group aims to further the chemistry of pyrroles, dipyrrins and prodigiosenes. This micro-review discusses each of these research areas in turn, focussing on our achievements thus far.
Publikováno v:
ChemInform. 40
Sulfenyl groups are attracting interest as masking/protectinggroups for pyrroles. A facile one-step synthesis of sulfenyl pyrroles,involving the reaction of pyrroles with N-(aryl-and alkyl-thio)phthalimides in the presence of MgBr 2 ,is reported and
Publikováno v:
ChemInform. 39
The asymmetric oxidation of prochiral 2-(arylsulfenyl)pyrroles has been investigated. A marked electronic effect within the substrate significantly influenced the degree of enantioselectivity obtai...
Autor:
Idralyn Q. Alarcon, Garrison E. Beye, Dale E. Ward, Marcelo Sales, H. Martin Gillis, Vishal Jheengut
Publikováno v:
The Journal of organic chemistry. 72(5)
The aldol reaction of tetrahydro-4H-thiopyranone with 1,4-dioxa-8-thiaspiro[4.5]decane-6-carboxaldehyde (I) gives four possible diastereomeric adducts (II). Aldol reactions of I with each of the diastereomers of II and their corresponding methoxymeth
Autor:
Dale E. Ward, K Saravanan, M. Abdul Rasheed, Olukayode T. Akinnusi, H. Martin Gillis, Pradip K. Sasmal
Publikováno v:
Organic letters. 8(12)
Meso 1,9-diketones (six to seven stereocenters) are readily obtained by stepwise or simultaneous two-directional aldol reactions of tetrahydro-4H-thiopyran-4-one with a thiopyran-derived aldehyde or dialdehyde. Enantioselective enolizations of these
Autor:
George T. Achonduh, Dale E. Ward, Garrison E. Beye, M. Abdul Rasheed, Vishal Jheengut, H. Martin Gillis
Publikováno v:
Synthesis. 2007:e1-e1
Tetrahydro-4 H-thiopyran-4-one was prepared in >75% yield by treatment of dimethyl 3,3′-thiobispropanoate with NaOMe (generated in situ) in THF solution and decarboxylation of the resulting methyl tetrahydro-4-oxo-2 H-thiopyran-3-carboxylate in ref