Zobrazeno 1 - 10 of 24 pro vyhledávání: '"H. Lars Deubner"'
1
Akademický článek
Magnetic moment of ^{207}Pb and the hyperfine splitting of ^{207}Pb^{81+}
Autor: Verena Fella, Leonid V. Skripnikov, Wilfried Nörtershäuser, Magnus R. Buchner, H. Lars Deubner, Florian Kraus, Alexei F. Privalov, Vladimir M. Shabaev, Michael Vogel
Publikováno v: Physical Review Research, Vol 2, Iss 1, p 013368 (2020)
We performed nuclear magnetic resonance measurements on lead(II) nitrate Pb(NO_{3})_{2} in aqueous solution and on the hexafluoridoplumbate(IV) [PbF_{6}]^{2−} ion in acetonitrile. Combined with new relativistic coupled cluster and relativistic dens
Externí odkaz: https://doaj.org/article/72cf096c1f344d7db4b5ea8e399ac180
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2
Akademický článek
Redetermination of the crystal structure of ThI4
Autor: H. Lars Deubner, Florian Kraus
Publikováno v: IUCrData, Vol 3, Iss 2, p x180201 (2018)
Single crystals of ThI4, thorium(IV) tetraiodide, were grown from thorium dioxide and aluminium triiodide. In comparison with the structure model reported previously for this compound [Zalkin et al. (1964). Inorg. Chem. 3, 639–644], we have determi
Externí odkaz: https://doaj.org/article/64156629faf1421fa47b47548a71ab51
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3
Surprises in the Solvent-Induced Self-Ionization in the Uranium Tetrahalide UX4 (X = Cl, Br, I)/Ethyl Acetate System
Autor: H. Lars Deubner, Tim Graubner, Magnus R. Buchner, Florian Weigend, Sergei I. Ivlev, Antti J. Karttunen, Florian Kraus
Publikováno v: ACS Omega. 7:11995-12003
Funding Information: We thank the Deutsche Forschungsgemeinschaft for funding. T.G. thanks the HPC-EUROPA3 (INFRAIA-2016-1-730897) for a travel grant and the computing resources provided by CSC, the Finnish IT Center for Science. Publisher Copyright:
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::7f70f3faf314d3eb79a9c85f67804578
https://doi.org/10.1021/acsomega.2c00175
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4
Reactions of ThX 4 (X=F, Cl, Br, I) with Liquid Ammonia‐Crystal Structures and a Theoretical Study of Ammine Thorium(IV) Halide Ammoniates
Autor: Antti J. Karttunen, H. Lars Deubner, Tim Graubner, Florian Kraus, Florian Weigend
Publikováno v: European Journal of Inorganic Chemistry. 2021:2787-2796
Supplementary data not published with Aalto affiliation. Funding Information: We thank the Deutsche Forschungsgemeinschaft for funding and Dr. Matthias Müller for helping with the single crystal measurement on [Th(NH)]Cl ⋅ 4NH. We thank Dr. Matthi
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b6f1b302c0cf8a2c76646817fdb2867b
https://doi.org/10.1002/ejic.202100383
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6
Complexes featuring a linear [N≡U≡N] core isoelectronic to the uranyl cation
Autor: H. Lars Deubner, Stefan S. Rudel, Florian Kraus, Antti J. Karttunen, Matthias Müller
Publikováno v: Nature Chemistry. 12:962-967
The aqueous chemistry of uranium is dominated by the linear uranyl cation [UO2]2+, yet the isoelectronic nitrogen-based analogue of this ubiquitous cation, molecular [UN2], has so far only been observed in an argon matrix. Here, we present three diff
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::c423ee480d7ab35faecbf8a973fb94bd
https://doi.org/10.1038/s41557-020-0505-5
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7
A brief visit to the BeCl2/ZnCl2 system and the prediction of a new polymorph of ZnCl2
Autor: Jascha Bandemehr, Antti J. Karttunen, Florian Kraus, H. Lars Deubner
Publikováno v: Zeitschrift für Naturforschung B. 75:491-496
Reactions of zinc chloride with beryllium chloride in the molar ratios of 1:1 and 3:2 at T = 300°C in sealed ampoules lead to the formation of the two compounds Be1− x Zn x Cl2 (x = 0.563(2) and 0.489(3), respectively). Their composition and cryst
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f21a90aa1e155a73f097004320c858d2
https://doi.org/10.1515/znb-2020-0023
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9
Binary Lead Fluoride Pb3F8
Autor: H. Lars Deubner, Jan Herritsch, Benedikt P. Klein, Jörn Schmedt auf der Günne, Claudio K. Krug, Sergei I. Ivlev, J. Michael Gottfried, Jascha Bandemehr, Stefan R. Kachel, Maik Schöniger, Jamal N. M. Aman, Antti J. Karttunen, Lukas Ruppenthal, Malte Sachs, Florian Kraus
Publikováno v: Chemistry – A European Journal. 25:15656-15661
The binary lead fluoride Pb3F8 was synthesized by the reaction of anhydrous HF with Pb3O4 or by the reaction of BrF3 with PbF2. The compound was characterized by single-crystal and powder X-ray diffraction, IR, Raman, and solid-state MAS 19F NMR spec
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::7b8f1a90186258700e93dd64deac9221
https://doi.org/10.1002/chem.201903954
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10
A spatially separated [KBr6]5− anion in the cyanido-bridged uranium(IV) compound [U2(CN)3(NH3)14]5+[KBr6]5−·NH3
Autor: Florian Kraus, H. Lars Deubner
Publikováno v: Zeitschrift für Naturforschung B. 75:111-116
The reaction of uranium tetrabromide with potassium cyanide in anhydrous liquid ammonia at room temperature leads to the formation of brown crystals of [U2(CN)3(NH3)14]5+ [KBr6]5− · NH3. We determined the crystal structure of the compound by singl
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::db4f3da552c702d63afbbd6c8f1b9bae
https://doi.org/10.1515/znb-2019-0161
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