Zobrazeno 1 - 10
of 91
pro vyhledávání: '"H. L. Anderson"'
Publikováno v:
Thermochimica Acta. 364:59-69
The alcoholysis of acetyl chloride, propionyl chloride and butyryl chloride with some alcohols in acetone and toluene has been investigated by means of calorimetric measurements. Furthermore a comparison with benzoyl chloride has been made. In the ca
Publikováno v:
Thermochimica Acta. 364:35-45
The alcoholysis of acetyl chloride under various reaction conditions has been investigated by isoperibolic calorimetry and HPLC-analysis. Non-linear kinetic evaluation has been realized by the program TA-kin 3.3 on the basis of temperature and concen
Publikováno v:
Thermochimica Acta. 364:47-58
The ethanolysis of acetyl chloride has been compared to the methanolysis and the hydrolysis, as well as to the reaction with n -propanol, n -butanol and n -pentanol in acetone and in toluene, to reveal chain-length effects. Pentanol, heptanol and non
Autor:
H. L. Anderson, Marek Maciejewski, R. Nomen, Michael E. Brown, H.O. Desseyn, Tong B. Tang, J. Opfermann, Jiří Málek, R. Keuleers, B. Roduit, Takefumi Mitsuhashi, A. Kemmler, Alan K. Burnham, J. Sempere, J.F. Janssens, R. Strey, Chao-Rui Li, Sergey Vyazovkin
Publikováno v:
Thermochimica Acta. 355:125-143
Part A of this series of papers (Parts B to E follow) presents the data and methods used, as well as the results obtained by participants in the ICTAC Kinetics Project. The isothermal and non-isothermal data sets provided were based on a hypothetical
Publikováno v:
Thermochimica Acta. 332:33-53
In 1994 the decomposition of calciumoxalate monohydrate as a three-step reaction has been investigated by 13 labs using the TG-method. The authors working group performed objective kinetic evaluations of 144 TG data sets obtained from the same charge
Publikováno v:
Thermochimica Acta. 310:179-184
Investigations in chemical safety are necessary in case that the reaction course depends on changes of the reaction conditions sensitively. To break off a conversion in a hazardous situation, the precision calorimeter ACTRON 5 is equipped with two sa
Publikováno v:
Thermochimica Acta. 310:95-99
Polyethers, which are produced by alcoholysis of oxiranes, are often used as solvents in chemical plants. The spectra of the products can be influenced by the choice of the catalyst (acid or base). The results of the base-catalyzed ethanolysis of 1,2
Publikováno v:
Thermochimica Acta. 310:161-165
Differential scanning calorimetry is well suited to record heat productions of chemical and physical processes as data for the following kinetic analysis. To obtain kinetic parameters of complex reactions, nonlinear optimization methods have to be us
Publikováno v:
Thermochimica Acta. 310:141-145
Acetylation of different hexanediols as a complex reaction has been investigated by calorimetry. The calorimetric curves demonstrate that the reaction rate depends on the molecular structure. In case of 1,6- and 2,5-hexanediols, the activation parame
Publikováno v:
Thermochimica Acta. 310:173-178
The kinetic control of exothermic reactions plays an important role in chemical safety technology. Predictions of thermal explosions by runaway, e.g. redox reactions, poly reactions, and decompositions, are required in case of simple as well as of co