Zobrazeno 1 - 10
of 191
pro vyhledávání: '"H. Kloosterziel"'
Autor:
H. Kloosterziel, H. J. Backer
Publikováno v:
Recueil des Travaux Chimiques des Pays-Bas. 71:295-301
Hammett's substitution constant σ for the methylsulphonyl group has been determined, giving σ-meta-CH3SO2 = 0.615 (0.6522) and two values for σ-para-CH3SO2 viz. + 1.15 for the substituted phenol and aniline and + 0.73 for the benzoic acid. This in
Publikováno v:
Recueil des Travaux Chimiques des Pays-Bas. 81:947-957
Thermal decarboxylation of sodium trichloroacetate in 1,2-dimethoxyethane yields NaCl, CO2, CO, CCl4, perchloroisopropenyl acetate (I) and perchloro-1,2-dimethylenecyclobutane (II). Strong evidence is presented for the intermediate formation of trich
Autor:
H. Kloosterziel, G. J. Heiszwolf
Publikováno v:
Recueil des Travaux Chimiques des Pays-Bas, 89(4), 413-416. Royal Netherlands Chemical Society
Linear relations of proton chem. shifts are given for open-chain anions such as cis-1-trans-2-buta-1,3-diene sulfinate anion and trans-1-methylpentadienyl anion and for trans-(substituted phenyl)allyl anions. [on SciFinder (R)]
Publikováno v:
Recueil des Travaux Chimiques des Pays-Bas. 71:1231-1234
Publikováno v:
Recueil des Travaux Chimiques des Pays-Bas. 80:740-746
The thermal decarboxylation of alkali trichloroacetates in aprotic solvents in the presence of olefins has been investigated. The isolation of dichlorocyclopropanes in good yields demonstrates the formation of CCl2 as an intermediate. By this method,
Autor:
H. J. Backer, H. Kloosterziel
Publikováno v:
Recueil des Travaux Chimiques des Pays-Bas. 71:373-378
Le 9,9-bis-methylthio-thioxanthene-10-dioxyde (Ib), qui se forme par thiomethylation du thioxanthene-10-dioxyde (la), peut etre regarde comme vinylogue des 1,1,1,1-disulfuredisulfones. L'hydrolyse acide engendre le thioxanthone-10-dioxyde (IV) et dif
Autor:
H. J. Backer, H. Kloosterziel
Publikováno v:
Recueil des Travaux Chimiques des Pays-Bas. 71:361-372
L'observation que le groupe carbonyle de la “sulfobenzophenone” (I) est reduit par chauffage avec l'hydrazine nous a amenes a etudier le comportement de quelques autres sulfonylcetones, specialement de celles ou le groupe sulfonyle, soit par prox
Autor:
H. J. Backer, H. Kloosterziel
Publikováno v:
Recueil des Travaux Chimiques des Pays-Bas. 72:655-659
N-acetyl-4-methylsulphonyl-2,6-xylidine (I) has been prepared by the convenient method used before, involving thiocyanation of 2,6-xylidine and reduction of the thiocyano group with LiAlH4, followed by methylation and subsequent oxidation of N-acetyl
Autor:
A. P. ter Borg, H. Kloosterziel
Publikováno v:
Recueil des Travaux Chimiques des Pays-Bas. 84:245-250
The rate of the interconversion of 2- and 1-phenylcycloheptatriene upon heating has been measured. These 1-5 shifts - in which the phenyl group is attached to the non-shifting double bond — are somewhat faster than in unsubstituted cycloheptatriene
Autor:
H. Kloosterziel, J. A. A. van Drunen
Publikováno v:
Recueil des Travaux Chimiques des Pays-Bas, 88(9), 1084-1087. Royal Netherlands Chemical Society
NMR spectroscopy reveals that the reaction between hepta-1,3,5-triene and potassium amide yields the all-trans heptatrienyl anion, which readily isomerizes to the cycloheptadienyl anion.