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Akademický článek
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Autor:
Yann Gauduel, H. Gelabert
Publikováno v:
Chemical Physics. 256:333-350
We report infrared and visible femtosecond spectroscopic data on primary steps of an electron–proton reaction in aqueous concentrated solutions ([H2O]/[HCl]=5 and 7, [D2O]/[DCl]=7). After an initial electron photodetachment triggered by a two-photo
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::4e0bc2ceb8848a0b08064f112220086e
https://doi.org/10.1016/s0301-0104(00)00112-9
https://doi.org/10.1016/s0301-0104(00)00112-9
Publikováno v:
Journal of the American Chemical Society. 122:5082-5091
The primary steps of a one-electron reduction of a disulfide molecule (cystamine) by the infrared p-like state of an excited hydrated electron have been investigated by femtosecond laser spectroscopy. The initial electron photodetachment from chlorid
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::426c2e6be952fe06f441704ce0e8ebb7
https://doi.org/10.1021/ja9933543
https://doi.org/10.1021/ja9933543
Publikováno v:
The Journal of Physical Chemistry A. 102:7795-7803
An ultrafast presolvation reaction involving IR-excited hydrated electrons and bivalent metal cations (Cd2+)aq was investigated at the femtosecond time scale. The initial electron photodetachment i...
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::d6f56b54ebfce58bb27fce01de0c7ade
https://doi.org/10.1021/jp980804p
https://doi.org/10.1021/jp980804p
Publikováno v:
Journal of Molecular Liquids. 78:111-122
Femtosecond spectroscopy of aqueous ionic solutions represents a good tool for the study of elementary chemical steps at the microscopic level. Ultrafast electron transfer processes are investigated at 294K.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::9d8a91d4063842e316601108238a0e36
https://doi.org/10.1016/s0167-7322(98)00086-5
https://doi.org/10.1016/s0167-7322(98)00086-5
Publikováno v:
Journal of Radioanalytical and Nuclear Chemistry. 232:125-129
With the intensive development of ultrafast spectroscopic techniques, reaction dynamics and transition states can be investigated at the subpicosecond time scale (0.05–3 ps). Aqueous ionic solutions represent a paradigm for the characterization of
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::1655545e0a9a548fe735d19f0332f748
https://doi.org/10.1007/bf02383726
https://doi.org/10.1007/bf02383726
Publikováno v:
The Journal of Physical Chemistry A. 101:8979-8986
The elementary steps of an electron photodetachment triggered by the UV excitation of pure liquid dimethyl sulfide, (CH3)2S, have been investigated by femtosecond absorption UV−IR spectroscopy at 294 K. The buildup of a long-lived UV band centered
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::60bd3724203a69189ab40e72a8213b49
https://doi.org/10.1021/jp9720754
https://doi.org/10.1021/jp9720754
Publikováno v:
Journal de Chimie Physique. 93:1808-1827
Dans le cadre d'une etude ab initio, menee au niveau MCSCF, le radical hydronium H 3 O. est hydrate au milieu d'une cavite dielectrique spherique de differents rayons, en utilisant les constantes dielectriques statique ou optique de l'eau liquide. Le
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::5b0941b8603085ce83850b000f6c2207
https://doi.org/10.1051/jcp/1996931808
https://doi.org/10.1051/jcp/1996931808
Publikováno v:
Journal de Chimie Physique. 93:1608-1627
Les premieres etapes d'un transfert d'electron dans une solution de chlorure de sodium sont etudiees par spectroscopie d'absorption femtoseconde du solute ionique. L'influence du rapport moleculaire (R = [H 2 O]/[NaCl]) sur les configurations electro
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::52a19fa365f3556c3ee9e88d8f320b0c
https://doi.org/10.1051/jcp/1996931608
https://doi.org/10.1051/jcp/1996931608