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Autor:
† Eun-il Kim, David W. Thompson, Christiana Xin Zhang, Donald V. Scaltrito, Hong-Chang Liang, Kenneth D. Karlin, Gerald J. Meyer, Brett M. Showalter, John P. Toscano, H. C. Fry, Ryan M. Kretzer
Publikováno v:
Inorganic chemistry. 40(18)
Pulsed light excitation of [CuI(TMPA)(CO)]+ in organic solvents at room-temperature results in rapid, k > 108 s-1, release of carbon monoxide to yield the solvento complex, [CuI(TMPA)(S)]+. The dynamics of this process and the subsequent rebinding of