Zobrazeno 1 - 10
of 146
pro vyhledávání: '"H. Buist"'
Publikováno v:
SynOpen, Vol 02, Iss 02, Pp 0168-0175 (2018)
Abstract The total synthesis of isotopically labelled (9R,10S)-dihydrosterculic acid, a usual cyclopropane fatty acid with biologically relevant toxicity upon desaturation in vivo, is reported. A diastereoselective Corey–Chaykovsky reaction was
Externí odkaz:
https://doaj.org/article/2d3c7bfe259b46c889a94febc691f7ac
Autor:
Jurriaan F. H. Buist, Benjamin Sanderse, Svetlana Dubinkina, Cornelis W. Oosterlee, Ruud A. W. M. Henkes
Publikováno v:
Buist, J F H, Sanderse, B, Dubinkina, S, Oosterlee, C W & Henkes, R A W M 2023, ' Energy-consistent formulation of the pressure-free two-fluid model ', International Journal for Numerical Methods in Fluids, vol. 95, no. 5, pp. 869-898 . https://doi.org/10.1002/fld.5168
International Journal for Numerical Methods in Fluids
International Journal for Numerical Methods in Fluids, 95(5)
International Journal for Numerical Methods in Fluids, 95(5), 869-898. John Wiley and Sons Ltd
International Journal for Numerical Methods in Fluids
International Journal for Numerical Methods in Fluids, 95(5)
International Journal for Numerical Methods in Fluids, 95(5), 869-898. John Wiley and Sons Ltd
The pressure-free two-fluid model (PFTFM) is a recent reformulation of the one-dimensional two-fluid model (TFM) for stratified incompressible flow in ducts (including pipes and channels), in which the pressure is eliminated through intricate use of
Publikováno v:
Plant Physiology. 182:730-738
In previous work, we identified a triple mutant of the castor (Ricinus communis) stearoyl-Acyl Carrier Protein desaturase (T117R/G188L/D280K) that, in addition to introducing a double bond into stearate to produce oleate, performed an additional roun
Publikováno v:
Tetrahedron: Asymmetry. 24:165-168
(9 R ,10 S )-Dihydrosterculic acid has been prepared from ( S S , S S )-1,1-bis( p -tolylsulfinyl)methane in a sequence involving an asymmetric Corey–Chaykovsky cyclopropanation and two sulfoxide/lithium exchange reactions. In most steps, the react
Publikováno v:
Cytopathology. 23:396-401
S. S. Hoo, A. Patel, H. Buist, K. Galaal, J. D. Hemming and R. Naik Borderline nuclear change, high-grade dyskaryosis not excluded: current concepts and impact on clinical practice Objective: Borderline nuclear change, high-grade dyskaryosis not excl
Publikováno v:
Bioorganic & Medicinal Chemistry Letters. 19:5146-5150
Chiral fluorine-tagged sulfoxides of known absolute configuration have been synthesized. These compounds are required as reference standards to validate a 19 F NMR-based micromethod for the stereochemical analysis of biosynthetic fatty acyl sulfoxide
Publikováno v:
Proceedings of the National Academy of Sciences. 105:14738-14743
It is estimated that plants contain thousands of fatty acid structures, many of which arise by the action of membrane-bound desaturases and desaturase-like enzymes. The details of “unusual” e.g., hydroxyl or conjugated, fatty acid formation remai
Publikováno v:
Bioorganic & Medicinal Chemistry Letters. 15:2799-2802
The stereochemistry of fatty acid desaturase-mediated sulfoxidation can be evaluated at micromolar concentrations of analyte using 19 F NMR in combination with a chiral shift reagent: ( S )-(+)-MPAA.
Publikováno v:
Helvetica Chimica Acta. 86:3688-3697
A series of 18-fluoro thiastearates were prepared and incubated with a yeast Δ9-desaturating system. The relative efficiency of desaturase-mediated sulfoxidation was monitored via19F-NMR analysis of the sulfoxide products, and a strong preference fo
Autor:
Patrick S. Covello, Stephen J. Ambrose, and Andrew R. S. Ross, Peter H. Buist, Darwin W. Reed, Robert J. Sasata, Christopher K. Savile, Devin R. Polichuk
Publikováno v:
Journal of the American Chemical Society. 125:10635-10640
The mechanism by which the fatty acid acetylenase of Crepis alpina catalyzes crepenynic acid ((9Z)-octadeca-9-en-12-ynoic acid) production from linoleic acid has been probed through the use of kinetic isotope effect (KIE) measurements. This was accom