Zobrazeno 1 - 10
of 18
pro vyhledávání: '"Guy Hurtrez"'
Publikováno v:
European Polymer Journal. 41:313-318
Well-defined block copolymers were obtained from 4-hydroxy-butyl-2-bromoisobutyrate dual initiator, combining tert -butylmethacrylate ATRP and e -caprolactone ROP in a one-step process. Using AlEt 3 as coinitiator in a ROP catalytic process, the vari
Publikováno v:
Journal of Applied Polymer Science. 98:1339-1343
We developed a colorimetric method to follow and to control the complete transformation of an alcohol into an alkoxide. It was first tested on a small molecule and then extended to a macroinitiator. It allows us to obtain a final product without resi
Publikováno v:
Journal of Polymer Science Part A: Polymer Chemistry. 43:2440-2447
Well-defined macromonomers of poly(ethylene oxide) and poly(tert-butyl methacrylate) were obtained by anionic polymerization induced directly by the carbanion issued from 2-methyl-2-oxazoline. When ethylene oxide was added to this carbanion with lith
Publikováno v:
Journal of Polymer Science Part A: Polymer Chemistry. 42:1745-1751
Three alternative routes, using the heterobifunctional macroinitiator technique, have been developed to obtain polystyrene–poly(tert-butyl methacrylate)–poly(ethylene oxide) triarm star block copolymers. Only the route showing the reverse initiat
Publikováno v:
Journal of Polymer Science Part A: Polymer Chemistry. 41:3329-3335
The reactions of polystyryllithium and potassium on dimethoxymethyl 1,1-diphenylethylene derivatives were studied in different solvents. In a polar medium, A3 and A6 star types were formed according to the stoichiometry, whereas in a nonpolar medium,
Publikováno v:
Macromolecular Symposia. 183:29-34
We described the use of 1,1 diphenylethylene derivatives in the synthesis of well-defined star block copolymers. Classical end-capping of polystyryl carbanion with -CH 2 CH 2 OTBDMSi derivative gives a heterobifunctional macroinitiator leading to ABC
Publikováno v:
Polymer. 43:7133-7139
We have previously described a new route to A 2 B star block copolymers by a double addition–elimination reaction of a polystyryl carbanion with a particular 1,1-diphenylethylene derivative. By using the same reagent, we are now able to prepare A 2
Publikováno v:
Macromolecular Symposia. 161:97-102
We describe the synthesis and characterization of three-arm star block copolymers based on polystyrene, poly(ethylene oxide), poly(ϵ-caprolactone), poly(methyl methacrylate), poly(tert-butyl methacrylate) and poly(L-lactide) blocks. The copolymers w
Publikováno v:
Polymer Bulletin. 40:143-149
We describe the synthesis and the characterization of amphiphilic triarm star block copolymers based on polystyrene, poly(methyl methacrylate), poly(e caprolactone), poly(l lactide) and poly(ethylene oxide) blocks. This synthesis has been achieved by
Publikováno v:
Macromolecular Rapid Communications. 18:343-351
The synthesis of an amphiphilic triarm star copolymer based on polystyrene, poly(ethylene oxide) and poly(e-caprolactone) block has been achieved by a novel strategy which consists in the preparation of a diblock copolymer, polystyrene-block-poly(eth