Zobrazeno 1 - 10
of 15
pro vyhledávání: '"Guang-Xiong Duan"'
Publikováno v:
Chemistry – A European Journal. 27:1122-1126
Four silver thiolate clusters, [H3 O][(Ag3 S3 )(BF4 )@Ag27 (tBuS)18 (hfac)6 H2 O]⋅H2 O (1; hfac = hexafluoroacetylacetone), [(Ag3 S3 )(CF3 CO2 )@Ag30 (tBuS)16 (CF3 CO2 )9 (CH3 CN)4 ]⋅CF3 CO2 ⋅4 CH3 CN (2), [(Ag3 S3 )(MoO4 )@Ag30 (tBuS)16 (CF3 C
Publikováno v:
Materials Chemistry Frontiers. 4:2205-2222
Metal nanoclusters (NCs) consist of tens to hundreds of metal atoms with a diameter of
Publikováno v:
Nanoscale. 12:1617-1622
Thiols, alkynyls and phosphines are the most widely used organic ligands to attain atomically precise metal nanoclusters, while oxometalates as inorganic ligands have almost been neglected in this field. Here, we used oxometalates (e.g., MoO42− and
Publikováno v:
Crystal Growth & Design. 19:5791-5797
Variation of the reaction conditions with Cu powder, Cu(NO3)2, and tBuC≡CH as starting materials afforded three new Cu(I) alkynyl complexes, namely, [Cu14(tBuC≡C)10(NO3)4(MeOH)2]·H2O (1), Cu15(tBuC...
Autor:
Yunpeng Xie, Peng Jin, Takeshi Akasaka, Wangqiang Shen, Shuaifeng Hu, Xing Lu, Le Yang, Guang-Xiong Duan
Publikováno v:
Chemistry – A European Journal. 25:11538-11544
Successful isolation and characterization of a series of Er-based dimetallofullerenes present valuable insights into the realm of metal-metal bonding. These species are crystallographically identified as Er2 @Cs (6)-C82 , Er2 @C3v (8)-C82 , Er2 @C1 (
Publikováno v:
Nanoscale. 12(3)
Thiols, alkynyls and phosphines are the most widely used organic ligands to attain atomically precise metal nanoclusters, while oxometalates as inorganic ligands have almost been neglected in this field. Here, we used oxometalates (e.g., MoO42- and W
Publikováno v:
Chemistry - A European Journal. 24:6762-6768
tert-Butylphosphonic acid and lanthanide precursors were employed to construct two high-nuclearity hybrid silver(I)-ytterbium(III) phosphonate clusters: compound 1 consists of a Ag16 ethynide cluster fused with a trinuclear hydroxoytterbium phosphona
Publikováno v:
Nanoscale. 10:18915-18919
The tert-butylethynide ligand has been employed to construct an atomically precise all-tert-butylethynide-protected silver superatom nanocluster, Ag51(tBuC[triple bond, length as m-dash]C)32 (hereafter denoted as Ag51). The identity of Ag51 is confir
Publikováno v:
Inorganic Chemistry. 56:10412-10417
Phosphonate ligands as structure-directing components have been employed to construct four new high-nuclearity silver(I) sulfide-ethynide-thiolate clusters, in which silver(I) aggregates tBuC≡C⊃Ag3, tBuC≡C⊃Ag4, and 2tBuC≡C⊃Ag7 are bridged
Publikováno v:
Coordination Chemistry Reviews. 331:54-72
The high-nuclearity silver(I) clusters, a novel class of supramolecular assembly of silver(I) complexes, were usually prepared by incorporating silver ions with various ligands. Notably, a large number of argentophilic interactions exist in the high-