Detection of the Order-to-Disorder Transition in Block Copolymer Electrolytes Using Quadrupolar 7 Li NMR Splitting

Autor: Grundy, LS, Sethi, GK, Galluzzo, MD, Loo, WS, Maslyn, JA, Teran, AA, Thelen, JL, Timachova, K, Reimer, JA, Madsen, LA, Balsara, NP

Publikováno v: ACS Macro Letters, vol 8, iss 2

The order-to-disorder transition temperature (T ODT ) in a series of mixtures of polystyrene-b-poly(ethylene oxide) (SEO) and lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) salt is identified by the disappearance of a quadrupolar 7 Li NMR triple

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https://escholarship.org/uc/item/6fs2f0vr

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An ordered, self-assembled nanocomposite with efficient electronic and ionic transport.

Autor: Quill TJ; Department of Materials Science and Engineering, Stanford University, Stanford, CA, USA., LeCroy G; Department of Materials Science and Engineering, Stanford University, Stanford, CA, USA., Halat DM; Department of Chemical and Biomolecular Engineering and College of Chemistry, University of California, Berkeley, CA, USA.; Materials Sciences Division and Joint Center for Energy Storage Research, Lawrence Berkeley National Laboratory, Berkeley, CA, USA., Sheelamanthula R; Physical Science and Engineering Division, King Abdullah University of Science and Technology (KAUST), Thuwal, Saudi Arabia., Marks A; Department of Materials Science and Engineering, Stanford University, Stanford, CA, USA., Grundy LS; Department of Chemical and Biomolecular Engineering and College of Chemistry, University of California, Berkeley, CA, USA.; Materials Sciences Division and Joint Center for Energy Storage Research, Lawrence Berkeley National Laboratory, Berkeley, CA, USA., McCulloch I; Physical Science and Engineering Division, King Abdullah University of Science and Technology (KAUST), Thuwal, Saudi Arabia.; Department of Chemistry, University of Oxford, Oxford, UK., Reimer JA; Department of Chemical and Biomolecular Engineering and College of Chemistry, University of California, Berkeley, CA, USA.; Materials Sciences Division and Joint Center for Energy Storage Research, Lawrence Berkeley National Laboratory, Berkeley, CA, USA., Balsara NP; Department of Chemical and Biomolecular Engineering and College of Chemistry, University of California, Berkeley, CA, USA.; Materials Sciences Division and Joint Center for Energy Storage Research, Lawrence Berkeley National Laboratory, Berkeley, CA, USA., Giovannitti A; Department of Materials Science and Engineering, Stanford University, Stanford, CA, USA. ag19@stanford.edu., Salleo A; Department of Materials Science and Engineering, Stanford University, Stanford, CA, USA. asalleo@stanford.edu., Takacs CJ; Stanford Synchrotron Radiation Lightsource, SLAC National Accelerator Laboratory, Menlo Park, CA, USA. ctakacs@slac.stanford.edu.

Publikováno v: Nature materials [Nat Mater] 2023 Mar; Vol. 22 (3), pp. 362-368. Date of Electronic Publication: 2023 Feb 16.

Difference between approximate and rigorously measured transference numbers in fluorinated electrolytes.

Autor: Shah DB; Department of Chemical and Biomolecular Engineering, University of California, 201 Gilman Hall, Berkeley, CA 94720-1462, USA. nbalsara@berkeley.edu., Nguyen HQ, Grundy LS, Olson KR, Mecham SJ, DeSimone JM, Balsara NP

Publikováno v: Physical chemistry chemical physics : PCCP [Phys Chem Chem Phys] 2019 Apr 21; Vol. 21 (15), pp. 7857-7866. Date of Electronic Publication: 2019 Mar 27.