Zobrazeno 1 - 10
of 58
pro vyhledávání: '"Gregory T. Whiteker"'
Autor:
Jing Yu, Xiaoyong Li, Suhelen Vásquez Céspedes, Min Sheng, Gregory T. Whiteker, Nicola J. Webb, Qiang Yang, Craig Tucker
Publikováno v:
Organic Process Research & Development. 24:916-939
Dimethyl sulfoxide (DMSO) is widely used as a solvent for chemical reactions, as a cosolvent for crop protection formulations, and in medicines for topical administration of drugs. The potential ex...
Autor:
Yu Lu, Hough Nicole, Kevin G. Meyer, Nakyen Choy, Kenneth E. Stockman, Yuanming Zhu, Megan A. Cismesia, Nicola J. Webb, James M. Renga, Jerzy Klosin, Xiaoyong Li, David J. Couling, Elizabeth O. McCusker, Nicholas R. Babij, Richard B. Rogers, Peter L. Johnson, Gregory T. Whiteker
Publikováno v:
Green Chemistry. 22:6047-6054
The design and synthesis of the broad-spectrum fungicide, florylpicoxamid, embodies multiple Green Chemistry principles. The active ingredient was strategically designed to deliver maximum biological activity and rapidly degrade after application to
Autor:
Gregory T. Whiteker
Publikováno v:
Organic Process Research & Development. 23:2109-2121
This review discusses specific examples of the application of the 12 principles of green chemistry from the crop protection industry. Many of the examples are operated on a multiton scale. Although...
Publikováno v:
Organic Process Research & Development. 23:2253-2260
A highly stereoselective and efficient synthesis of (4S,5S,6S)-6-(benzyloxy)-5-phenoxy-4-propoxyheptanal, a key intermediate for syntheses of picolinamide fungicides, is described in this report. The synthesis features a scalable allylpropyl ether pr
Autor:
Kim E. Arndt, James M. Renga, Gary Roth, Qiang Yang, Gregory T. Whiteker, Jerzy Klosin, Robert D. J. Froese, Yuanming Zhu, Belgin Canturk
Publikováno v:
Organic Process Research & Development. 23:2166-2174
The development of a new synthesis of 6-aryl-5-fluoropicolinate herbicides is described. This general route employs the halogen exchange (halex) reaction of tetrachloropicolinonitrile to give a mix...
Autor:
Gregory T. Whiteker, Robert D. J. Froese, Jerzy Klosin, Fangzheng Li, Amaruka Hazari, Michael L. Tulchinsky
Publikováno v:
Organometallics. 38:2233-2238
The synthesis and characterization of an analog of the Xantphos ligand that is geometrically incapable of coordination of the xanthene bridging oxygen atom is reported. This new ligand, XL-Xantphos, ((9,9-dimethyl-9H-xanthene-4,5-diyl)bis(4,1-phenyle
Autor:
Bruce S. Holden, Gregory T. Whiteker, Arvind Jaganathan, Zhao Li, Charles L. Liotta, Carol Gelbaum, Jason S. Fisk, Paul C. Gould, Zachary S. Campbell, Pamela Pollet
Publikováno v:
New Journal of Chemistry. 41:15420-15432
The Pd-catalyzed Suzuki coupling reactions of a series of aryl chlorides and aryl bromides containing basic nitrogen centers with arylboronic acids in water in the absence of added base are reported. The reactions proceed either partially or entirely
Autor:
James M. Renga, Daniel J. Arriola, Justin W. Shearer, Robert D. J. Froese, Gregory T. Whiteker, Thomas H. Peterson
Publikováno v:
The Journal of Organic Chemistry. 81:10672-10682
The Halex reaction of pentachloropyridine with fluoride ion was studied experimentally and computationally with a modified ab initio G3MP2B3 method. The G3 procedure was altered, as the anionic transition state optimizations failed due to the lack of
Autor:
Qiang Yang, Lawrence C. Creemer, Peter L. Johnson, James A. Knobelsdorf, Benjamin M. Nugent, Carl V. De Amicis, Sarah Ryan, Elizabeth O. McCusker, Gregory T. Whiteker, Nakyen Choy, Beth A. Lorsbach, Nicole M. Hewlett, Fangzheng Li, Belgin Canturk, Nicholas R. Babij, Michelle Smith
Publikováno v:
Organic Process Research & Development. 20:661-667
The 1H and 13C NMR chemical shifts of 48 industrially preferred solvents in six commonly used deuterated NMR solvents (CDCl3, acetone-d6, DMSO-d6, acetonitrile-d3, methanol-d4, and D2O) are reported. This work supplements the compilation of NMR data
Publikováno v:
Journal of the American Chemical Society, vol 140, iss 49
A methyl group on an arene, despite its small size, can have a profound influence on biologically active molecules. Typical methods to form a methylarene involve strong nucleophiles or strong and often toxic electrophiles. We report a strategy for a
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::ea923a09b71fef401ff60dcad80f7f34
https://escholarship.org/uc/item/46v866bm
https://escholarship.org/uc/item/46v866bm