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A short formal synthesis of ent-Cephalotaxine is achieved. The approach features a new Lewis acid mediated [2,3]-Stevens rearrangement of N-allylated prolineamide to generate a key quaternary stereogenic center. Additionally, a one-pot Parham–aldol
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=od______1222::81d097228fc05bed548fe6591f5c110b
http://urn.fi/URN:NBN:fi:jyu-201809214206
http://urn.fi/URN:NBN:fi:jyu-201809214206
Autor:
Gregorio, Giovanni Di1, Manna, Gianfranco La1, Paniagua, Juan Carlos2, Vilaseca, Eudald2 eudald@qf.ub.es
Publikováno v:
Journal of Molecular Structure: THEOCHEM. Mar2004, Vol. 673 Issue 1-3, p87. 6p.
