Zobrazeno 1 - 10
of 73
pro vyhledávání: '"Grant A, Broker"'
Publikováno v:
Acta Crystallographica Section E: Crystallographic Communications, Vol 73, Iss 10, Pp 1458-1464 (2017)
In the title compound, [Zn(C4H8NOS2)2(C12H10N4)], the ZnII atom exists within a NS4 donor set defined by two chelating dithiocarbamate ligands and a pyridyl-N atom derived from a terminally bound 4-pyridinealdazine ligand. The distorted coordination
Externí odkaz:
https://doaj.org/article/f996d9c68b844ee79709de7581bb6ca6
Autor:
Grant A. Broker, Edward R. T. Tiekink
Publikováno v:
Acta Crystallographica Section E, Vol 66, Iss 4, Pp o748-o748 (2010)
With the exception of the terminal hydroxy group [N—C—C—O = 53.8 (5)°], the cation of the title salt hydrate, C5H14NO+·C14H9O4S2−.H2O, is a straight chain. A twisted conformation is found for the anion [C—S—S—C = −87.44 (16)°]. In
Externí odkaz:
https://doaj.org/article/305d42022963484c807f8255b6805906
Autor:
Grant A. Broker, Edward R. T. Tiekink
Publikováno v:
Acta Crystallographica Section E, Vol 66, Iss 3, Pp o718-o718 (2010)
In the title hydrated salt, C4H15N32+·C14H8O4S2−·2H2O, the dication (with both terminal –NH2 groups protonated) adopts a U-shaped conformation, the Namine—C—C—Nazanium torsion angles being 57.9 (6) and 60.3 (6)°. The dianion is twisted:
Externí odkaz:
https://doaj.org/article/5aba65cef5bb4de8bce2c695fb8288fe
Publikováno v:
Acta Crystallographica Section E, Vol 66, Iss 3, Pp o569-o569 (2010)
In the title hydrate, C18H20BrO4P·H2O, a staggered conformation is found when the organic molecule is viewed down the central P—C bond, with the oxo and hydroxyl groups being diagonally opposite; each of the central P and C atoms has an S-configur
Externí odkaz:
https://doaj.org/article/66ee155bf57b40eea00a267689aecf46
Autor:
Grant A. Broker, Edward R. T. Tiekink
Publikováno v:
Acta Crystallographica Section E, Vol 66, Iss 3, Pp o705-o705 (2010)
The asymmetric unit of the title salt, 2C4H12NO+·C14H8O4S22−, contains an ethyl(2-hydroxy)aminium cation and half a 2,2′-disulfanediyldibenzoate anion, with the latter disposed about a twofold axis. The cation is a straight chain with the except
Externí odkaz:
https://doaj.org/article/ef4f5b58a0a3428eb9717d043b2b7a47
Publikováno v:
Acta Crystallographica Section E, Vol 66, Iss 1, Pp o98-o98 (2010)
In the title compound, C10H22NO6P, a staggered conformation is found when the molecule is viewed down the central P—C bond, with the oxo and hydroxy groups gauche to each other. The crystal structure features supramolecular chains of helical topolo
Externí odkaz:
https://doaj.org/article/b1b77244011847e5b4e779ca934f56c9
Publikováno v:
Acta Crystallographica Section E, Vol 66, Iss 1, Pp o99-o99 (2010)
In the title compound, C14H21FNO6P, a staggered conformation about the central P—C bond occurs, with the oxo and hydroxyl groups occupying diagonally opposite positions. The crystal structure features supramolecular chains mediated by O—H...O hyd
Externí odkaz:
https://doaj.org/article/c89c6626b7ee4adea4fe925448d5a6f7
Autor:
Edward R. T. Tiekink, Grant A. Broker
Publikováno v:
Acta Crystallographica Section E, Vol 64, Iss 12, Pp m1582-m1582 (2008)
A nearly linear coordination geometry for Au is found in the title compound, [Au(C9H9N2O3S)(C21H21P)]. The thiocarbamate ligand is orientated so that the aryl group is in close proximity to the Au atom, consistent with an Au...π contact [Au...Cg = 3
Externí odkaz:
https://doaj.org/article/cce44aba82654c84a4c884b6af5135a5
Publikováno v:
Acta Crystallographica Section E: Crystallographic Communications, Vol 73, Iss 10, Pp 1458-1464 (2017)
In the title compound, [Zn(C4H8NOS2)2(C12H10N4)], the ZnIIatom exists within a NS4donor set defined by two chelating dithiocarbamate ligands and a pyridyl-Natom derived from a terminally bound 4-pyridinealdazine ligand. The distorted coordination geo
Publikováno v:
Acta Crystallographica Section E: Crystallographic Communications
The mononuclear title compound features a Zn2+ ion coordinated by two symmetrically binding dithiocarbamate ligands and one end of a 4-pyridinealdazine molecule with the resulting NS4 donor set tending towards a square-pyramidal geometry.