Zobrazeno 1 - 10
of 17
pro vyhledávání: '"Graham M. Lee"'
Publikováno v:
Tetrahedron. 75:2106-2112
In this study we have studied the synthesis, characterization and catalytic activity of phosphinocopper(I) complexes [Cu(PPh3)3(NCCH3)][B(O2C6H4-4-R)2] (3a: R = H; 3b: R = Me; 3c: R = NO2) and [Cu(PPh3)3(NCCH3)][B(O2C6H3-3,5-di-tBu)2] (3d) containing
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::6224130f61f2322427529e88aa32782a
https://doi.org/10.1016/j.tet.2019.02.028
https://doi.org/10.1016/j.tet.2019.02.028
Publikováno v:
Journal of Organometallic Chemistry. 847:270-277
In this study, trifluoromethyl POCOP-type pincer complexes (iPrPOCOP)Ni(CF3) (1-CF3) and (iPrPOCOP)Pd(CF3) (2-CF3) are prepared. These complexes undergo Lewis acid-mediated fluoride abstraction to furnish cationic d8 difluorocarbene complexes of the
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::95ba6e083be7a31432ba34b2f4d7e965
https://doi.org/10.1016/j.jorganchem.2017.04.013
https://doi.org/10.1016/j.jorganchem.2017.04.013
Autor:
Russell P. Hughes, Daniel J. Harrison, Graham M. Lee, R. Tom Baker, Ilia Korobkov, Alicia S. C. Leung
Publikováno v:
Organometallics. 36:2853-2860
Cobalt fluorocarbene complex CpCo(═CF(CF3))(PPh2Me) (Cp = η5-cyclopentadienyl) reacts with para-substituted phenylacetylenes to furnish partially fluorinated cobaltacyclobutene complexes [Cp(PPh2Me)Co{κ2-C(Ar)═CHCF(CF3)}], which were isolated a
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::e970e21a18634776695dc08694022749
https://doi.org/10.1021/acs.organomet.7b00344
https://doi.org/10.1021/acs.organomet.7b00344
Publikováno v:
Catal. Sci. Technol.. 7:4996-5003
Using a high-throughput experimental procedure, a series of cobalt(III) complexes of the general formula CpRCo(I)(X)(L) were prepared and screened for their activity towards the catalytic nucleophilic fluorination of benzoyl chloride. A highly active
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::ce7a934083e98f3d0c901b9583886a30
https://doi.org/10.1039/c7cy01519d
https://doi.org/10.1039/c7cy01519d
Publikováno v:
Tetrahedron Letters. 57:5464-5468
A nickel catalyzed Suzuki coupling of arylboronic acids and novel bromodifluoromethyl(arylsulfonyl) compounds is described, providing an example of direct Csp2-CF2SO2Ar bond formation. High-throughput experimentation (HTE) was utilized for identifyin
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::8adc07af6c1a0f9a87bbaaf21bdd37c1
https://doi.org/10.1016/j.tetlet.2016.10.085
https://doi.org/10.1016/j.tetlet.2016.10.085
Autor:
Serge I. Gorelsky, David A. Dixon, R. Tom Baker, Julia M. Bayne, Monica Vasiliu, Ilia Korobkov, Matthew C. Leclerc, Daniel J. Harrison, Graham M. Lee
Publikováno v:
Journal of the American Chemical Society. 137:16064-16073
Four perfluoroalkyl cobalt(III) fluoride complexes have been synthesized and characterized by elemental analysis, multinuclear NMR spectroscopy, X-ray crystallography, and powder X-ray diffraction. The remarkable cobalt fluoride (19)F NMR chemical sh
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e7f082b880085bb1dbc39ca3cbae6193
https://doi.org/10.1021/jacs.5b12003
https://doi.org/10.1021/jacs.5b12003
Publikováno v:
Journal of the American Chemical Society. 135:18296-18299
Cobalt fluorocarbene complexes CpCo(═CFR(F))(PPh2Me) (Cp = η(5)-C5H5, R(F) = F or CF3) react with tetrafluoroethylene to give the metallacyclobutanes CpCo(κ(2)-CFR(F)CF2CF2-)(PPh2Me) in the first examples of cycloaddition reactions between perflu
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::5d45048bd91a07e6e57c8d1c0f67d8db
https://doi.org/10.1021/ja411503c
https://doi.org/10.1021/ja411503c
Autor:
Nathan R. Halcovitch, Christopher M. Vogels, Michael J. Geier, Christopher A. Gray, Andreas Decken, Taryn O'Neill, Andrew J. Flewelling, Eric G. Bowes, Michael I. Webb, Graham M. Lee, Haoxin Li, Stephen A. Westcott
Publikováno v:
Journal of Heterocyclic Chemistry. 51:157-161
A family of arylspiroborates has been prepared by the addition of either 4-tert-butylcatechol or 3,5-di-tert-butylcatechol to boric acid and an alkali metal hydroxide. All compounds were characterized fully using multinuclear NMR spectroscopy and by
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::710aa4f0e81a45774d1a8a878494e47a
https://doi.org/10.1002/jhet.1997
https://doi.org/10.1002/jhet.1997
Publikováno v:
Organometallics. 32:12-15
Unusual nucleophilic cobalt fluorocarbene complexes ([CoI]═CFR; R = F, CF3) are described. Only a handful of fluorocarbenes of first-row transition metals have been reported, and these have exhibited electrophilic reactivity at the metal–carbene
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::cd8fafbc6b48a1fcdd31496b86a7c6cd
https://doi.org/10.1021/om3010959
https://doi.org/10.1021/om3010959
Autor:
Nicole M. Hunter, Glen G. Briand, Andreas Decken, Graham M. Lee, Evan M. Owen, Jennifer Melanson
Publikováno v:
Polyhedron. 31:796-800
The reaction of Ph2BiCl with (PhS)Li or (2,6-Me2C6H3S)Li yielded [Ph2BiSPh]∞ (7) or Ph2BiS(2,6-Me2C6H3)] (8), respectively. Both compounds have been characterized by elemental analysis, melting point, FT-IR, FT-Raman, solution 1H and 13C{1H} NMR, a
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::e5414c74896eecd13ef5b3bcfec35461
https://doi.org/10.1016/j.poly.2011.11.011
https://doi.org/10.1016/j.poly.2011.11.011