Post-synthetic modulation of the charge distribution in a metal–organic framework for optimal binding of carbon dioxide and sulfur dioxide† †Electronic supplementary information (ESI) available: Synthetic details, structural data, figures, PXRD patterns, TGA, IR spectroscopic and sorption analyses. This material is available in the online version of paper. Correspondence of requests for materials should be addressed to S. Y. and M. S. CCDC 1580818–1580823, 1580825–1580829, 1580831, 1580832, 1580833, 1580834. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c8sc01959b

Autor: Li, Lei, da Silva, Ivan, Kolokolov, Daniil I., Han, Xue, Li, Jiangnan, Smith, Gemma, Cheng, Yongqiang, Daemen, Luke L., Morris, Christopher G., Godfrey, Harry G. W., Jacques, Nicholas M., Zhang, Xinran, Manuel, Pascal, Frogley, Mark D., Murray, Claire A., Ramirez-Cuesta, Anibal J., Cinque, Gianfelice, Tang, Chiu C., Stepanov, Alexander G., Yang, Sihai, Schroder, Martin

Publikováno v: Chemical Science

Modulation of pore environment is an effective strategy to optimize guest binding in porous materials.
Modulation of pore environment is an effective strategy to optimize guest binding in porous materials. We report the post-synthetic modificati

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=pmid________::1c1e9e7d6933dc780de0e729d0a5766c
http://europepmc.org/articles/PMC6369579

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Modulating supramolecular binding of carbon dioxide in a redox-active porous metal-organic framework

Autor: Lu, Zhenzhong, Godfrey, Harry G. W., da Silva, Ivan, Cheng, Yongqiang, Savage, Mathew, Tuna, Floriana, McInnes, Eric J. L., Teat, Simon J., Gagnon, Kevin J., Frogley, Mark D., Manuel, Pascal, Rudic, Svemir, Ramirez-Cuesta, Anibal J., Easun, Timothy L., Yang, Sihai, Schröder, Martin

Publikováno v: Nature Communications, Vol 8, Iss 1, Pp 1-10 (2017)
Nature communications, vol 8, iss 1
Lu, Z; Godfrey, HGW; Da Silva, I; Cheng, Y; Savage, M; Tuna, F; et al.(2017). Modulating supramolecular binding of carbon dioxide in a redox-active porous metal-organic framework. Nature Communications, 8. doi: 10.1038/ncomms14212. Lawrence Berkeley National Laboratory: Retrieved from: http://www.escholarship.org/uc/item/9h1322n3
Lu, Z, Godfrey, H, Da Silva, I, Cheng, Y, Savage, M, Tuna, F, Mcinnes, E, Teat, S J, Gagnon, K J, Frogley, M D, Manuel, P, Rudić, S, J. Ramirez-Cuesta, A, Easun, T L, Yang, S & Schroder, M 2017, ' Modulating Supramolecular Binding of Carbon Dioxide in a Redox-Active Porous Metal-Organic Framework ', Nature Communications, vol. 8, 14212 . https://doi.org/10.1038/ncomms14212

Hydrogen bonds dominate many chemical and biological processes, and chemical modification enables control and modulation of host–guest systems. Here we report a targeted modification of hydrogen bonding and its effect on guest binding in redox-acti

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=dedup_wf_001::b365ba058092ea668891132fee2790b3
https://doaj.org/article/d102796e45484256907a08dab1dbe753

Optimal Binding of Acetylene to a Nitro-Decorated Metal–Organic Framework

Autor: Duong, Thien D., Sapchenko, Sergey A., da Silva, Ivan, Godfrey, Harry G. W., Cheng, Yongqiang, Daemen, Luke L., Manuel, Pascal, Ramirez-Cuesta, Anibal J., Yang, Sihai, Schröder, Martin

Publikováno v: Journal of the American Chemical Society

We report the first example of crystallographic observation of acetylene binding to −NO2 groups in a metal–organic framework (MOF). Functionalization of MFM-102 with −NO2 groups on phenyl groups leads to a 15% reduction in BET surface area in M

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=pmid_dedup__::63f525a3fcf968b3e267448e24c20ce4