Cp 2 TiX Complexes for Sustainable Catalysis in Single‐Electron Steps

Autor: Daniel G. Enny, Robert A. Flowers, Theresa Olyschläger, Sven Hildebrandt, Godfred D. Fianu, Ruben B. Richrath, Andreas Gansäuer

Publikováno v: Chemistry – A European Journal. 24:6371-6379

We present a combined electrochemical, kinetic, and synthetic study with a novel and easily accessible class of titanocene catalysts for catalysis in single-electron steps. The tailoring of the electronic properties of our Cp2 TiX-catalysts that are

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::794811433b789acce81e83dbc9549b9c
https://doi.org/10.1002/chem.201705707

Cp

Autor: Ruben B, Richrath, Theresa, Olyschläger, Sven, Hildebrandt, Daniel G, Enny, Godfred D, Fianu, Robert A, Flowers, Andreas, Gansäuer

Publikováno v: Chemistry (Weinheim an der Bergstrasse, Germany). 24(24)

We present a combined electrochemical, kinetic, and synthetic study with a novel and easily accessible class of titanocene catalysts for catalysis in single-electron steps. The tailoring of the electronic properties of our Cp

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=pmid________::1c54a10d55a17c74ea558d8f6d345563
https://pubmed.ncbi.nlm.nih.gov/29327511

Substituent Effects and Supramolecular Interactions of Titanocene(III) Chloride: Implications for Catalysis in Single Electron Steps

Autor: Kim Daasbjerg, Andreas Gansäuer, Stefan Grimme, Rebecca Sure, Godfred D. Fianu, Dhandapani V. Sadasivam, Robert A. Flowers, Christian Kube

Publikováno v: Gansaeuer, A, Kube, C, Daasbjerg, K, Sure, R, Grimme, S, Fianu, G D, Sadasivam, D V & Flowers, R A 2014, ' Substituent Effects and Supramolecular Interactions of Titanocene(III) Chloride : Implications for Catalysis in Single Electron Steps ', Journal of the American Chemical Society, vol. 136, no. 4, pp. 1663-1671 . https://doi.org/10.1021/ja4121567

The electrochemical properties of titanocene(III) complexes and their stability in THF in the presence and absence of chloride additives were studied by cyclic voltammetry (CV) and computational methods. The anodic peak potentials of the titanocenes

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::26ecc3dae00f59f72f285a49fbdcaaa2
https://doi.org/10.1021/ja4121567

Front Cover: Cp2 TiX Complexes for Sustainable Catalysis in Single-Electron Steps (Chem. Eur. J. 24/2018)

Autor: Daniel G. Enny, Sven Hildebrandt, Robert A. Flowers, Godfred D. Fianu, Ruben B. Richrath, Theresa Olyschläger, Andreas Gansäuer

Publikováno v: Chemistry - A European Journal. 24:6282-6282

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::e295d438753eefcb957600068e855849
https://doi.org/10.1002/chem.201800784

Mechanistic study of the titanocene(III)-catalyzed radical arylation of epoxides

Autor: Daniel von Laufenberg, Antonius Michelmann, Christian Kube, Meriam Seddiqzai, Godfred D. Fianu, Andreas Gansäuer, Stefan Grimme, Tobias Dahmen, Maike Behlendorf, Robert A. Flowers, Dhandapani V. Sadasivam, Rebecca Sure

Publikováno v: Chemistry (Weinheim an der Bergstrasse, Germany). 21(1)

An atom-economical and catalytic arylation of epoxide-derived radicals is described. The key step of the catalytic system is a sequential electron and proton transfer for the rearomatization of the radical σ-complex and catalyst regeneration. Kineti

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::3563bb4180d616a85c30340b56022c02
https://pubmed.ncbi.nlm.nih.gov/25351963