Zobrazeno 1 - 10
of 94
pro vyhledávání: '"Glavatskiy, K."'
Autor:
Glavatskiy, K. S., Kulinskii, V. L.
Ability of dynamical systems to relax to equilibrium has been investigated since the invention of statistical mechanics, which establishes the connection between dynamics of many-body Hamiltonian systems and phenomenological thermodynamics. The key l
Externí odkaz:
http://arxiv.org/abs/1906.12041
Autor:
Kulinskii, V. L., Glavatskiy, K. S.
We show that fundamental thermodynamic relations can be derived from deterministic mechanics for a non-ergodic system. This extend a similar derivation for ergodic systems and suggests that ergodicity should not be considered as a requirement for a s
Externí odkaz:
http://arxiv.org/abs/1811.04591
Publikováno v:
Journal of Molecular Liquids 235, 119-125 (2017)
The approach of global isomorphism between the fluid and the Ising model is applied to obtain an expression for the surface tension of the Lennard-Jones fluid on the basis of the information about the Ising model. This is done in a broad interval of
Externí odkaz:
http://arxiv.org/abs/1608.05136
Autor:
Glavatskiy, K. S.
Validity of local equilibrium has been questioned for non-equilibrium systems which are characterized by delayed response. In particular, for systems with non-zero thermodynamic inertia, the assumption of local equilibrium leads to negative values of
Externí odkaz:
http://arxiv.org/abs/1507.07656
Autor:
Glavatskiy, K. S.
We show that the equations which describe irreversible evolution of a system can be derived from a variational principle. We suggest a Lagrangian, which depends on the properties of the normal and the so-called "mirror-image" system. The Lagrangian i
Externí odkaz:
http://arxiv.org/abs/1502.02122
Autor:
Glavatskiy, K. S., Bedeaux, D.
Nucleation is often accompanied by heat transfer between the surroundings and a nucleus of a new phase. The interface between two phases gives an additional resistance to this transfer. For small nuclei the interfacial curvature is high, which affect
Externí odkaz:
http://arxiv.org/abs/1310.3025
We determine thermodynamic stability conditions in terms of Helmholtz and Gibbs energies for sI clathrate hydrates with CH$_4$ and CO$_2$ at 278 K. Helmholtz energies are relevant for processing from porous rocks (constant volume), while Gibbs energi
Externí odkaz:
http://arxiv.org/abs/1307.6977
Autor:
Glavatskiy, K., Bedeaux, D.
In this paper we derive relations between the local resistivities inside the interfacial region and the overall resistances of the surface between two phases for a mixture. These resistivities are the coefficients in the force-flux relations for the
Externí odkaz:
http://arxiv.org/abs/0907.4591
Autor:
Glavatskiy, K. S., Bedeaux, D.
In this paper we calculate the transfer coefficients for evaporation and condensation of mixtures. We use the continuous profiles of various thermodynamic quantities through the interface, obtained in our previous works using the square gradient mode
Externí odkaz:
http://arxiv.org/abs/0907.1982
Autor:
Glavatskiy, K. S., Bedeaux, D.
In this paper we first apply the general analysis described in our first paper to a binary mixture of cyclohexane and $n$-hexane. We use the square gradient model for the continuous description of a non-equilibrium surface and obtain numerical profil
Externí odkaz:
http://arxiv.org/abs/0812.4386