Zobrazeno 1 - 8
of 8
pro vyhledávání: '"Giuseppe Spedalotto"'
Publikováno v:
ACS Omega, Vol 6, Iss 42, Pp 28162-28170 (2021)
Externí odkaz:
https://doaj.org/article/8dac5f8537af42c389fefa9ad94005a5
Autor:
Philipp Heim, Robert Gericke, Giuseppe Spedalotto, Marta Lovisari, Erik R. Farquhar, Aidan R. McDonald
Publikováno v:
Dalton Transactions. 52:2663-2671
The reaction between NiII salts and m-CPBA can lead to a potent formally NiIVO oxidant capable of arene hydroxylation, which decays to yield a meta-stable NiIII-phenolate.
Autor:
Philipp Heim, Giuseppe Spedalotto, Marta Lovisari, Robert Gericke, John O'Brien, Erik R. Farquhar, Aidan R. McDonald
Publikováno v:
Chemistry – A European Journal. 29
Autor:
Giuseppe, Spedalotto, Robert, Gericke, Marta, Lovisari, Erik R, Farquhar, Brendan, Twamley, Aidan R, McDonald
Publikováno v:
Chemistry (Weinheim an der Bergstrasse, Germany). 25(51)
Hydroxide-bridged high-valent oxidants have been implicated as the active oxidants in methane monooxygenases and other oxidases that employ bimetallic clusters in their active site. To understand the properties of such species, bis-μ-hydroxo-Ni
Publikováno v:
Advanced Materials Interfaces. 4
Publikováno v:
Advanced Materials Interfaces. 4:1601025
Publikováno v:
ACS Omega
ACS Omega, Vol 6, Iss 42, Pp 28162-28170 (2021)
ACS Omega, Vol 6, Iss 42, Pp 28162-28170 (2021)
Despite their potential role in enzymatic systems, there is a dearth of hydroxide-bridged high-valent oxidants. We recently reported the synthesis and characterization of NiIINiIII(μ-OH)2 (2) and Ni2III(μ-OH)2 (3) species supported by a dicarboxami
Autor:
Robert Gericke, Brendan Twamley, Aidan R. McDonald, Marta Lovisari, Erik R. Farquhar, Giuseppe Spedalotto
Publikováno v:
Chemistry – A European Journal
Hydroxide-bridged high-valent oxidants have been implicated as the active oxidants in methane monooxygenases and other oxidases that employ bimetallic clusters in their active site. To understand the properties of such species, bis-μ-hydroxo-NiII2 c