Zobrazeno 1 - 7
of 7
pro vyhledávání: '"Giulia Iadevaia"'
Publikováno v:
Chemical Science. 10:5258-5266
Template-directed synthesis is the biological method for the assembly of oligomers of defined sequence, providing the molecular basis for replication and the process of evolution. To apply analogous processes to synthetic oligomeric molecules, method
Complementary phenylacetylene oligomers equipped with phenol and phosphine oxide recognition sites form stable multiply H-bonded duplexes in toluene solution. Oligomers were prepared by Sonogashira coupling of diiodobenzene and bis-acetylene building
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d8b0a70f713167dd7af29ffa256b61f3
Publikováno v:
Chemical Science
Oligomeric molecules equipped with complementary H-bond recognition sites form stable duplexes in non-polar solvents. The use of a single H-bond between a good H-bond donor and a good H-bond acceptor as the recognition motif appended to a non-polar b
Autor:
Diego, Núñez-Villanueva, Giulia, Iadevaia, Alexander E, Stross, Michael A, Jinks, Jonathan A, Swain, Christopher A, Hunter
Publikováno v:
Journal of the American Chemical Society
Linear oligomers equipped with complementary H-bond donor (D) and acceptor (A) sites can interact via intermolecular H-bonds to form duplexes or fold via intramolecular H-bonds. These competing equilibria have been quantified using NMR titration and
Publikováno v:
Chemical Science
Six isomeric backbone combinations can be used interchangeably to construct stable H-bonded duplexes of similar stability.
The formation of well-defined supramolecular assemblies involves competition between intermolecular and intramolecular int
The formation of well-defined supramolecular assemblies involves competition between intermolecular and intramolecular int
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::93493c4030879a1b0077c2c54ace7821
https://www.repository.cam.ac.uk/handle/1810/252992
https://www.repository.cam.ac.uk/handle/1810/252992
A series of flexible oligomers equipped with phenol H-bond donors and phosphine oxide H-bond acceptors have been synthesised using reductive amination chemistry. H-bonding interactions between complementary oligomers leads to the formation of double-
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::502ca64aaa278077345c95658608fedd
https://www.repository.cam.ac.uk/handle/1810/251329
https://www.repository.cam.ac.uk/handle/1810/251329
Publikováno v:
Chemical Science. 13(44):13085-13093
Sandwich complexes formed by two zinc porphyrins and a diamine ligand (DABCO) have been used as a supramolecular template to direct the synthesis of triazole oligomers. Monomer units equipped with two polymerizable functional groups, an alkyne and an