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Publikováno v:
Magnetic Resonance in Chemistry. 34:638-645
binuclear complex [ AI,(p-OH),(C,,H,0,),(Na)4(H~O)4] was obtained, which is stable as the tetrahydrate and is observed even in the gas phase by electrospray mass spectrometry. With potassium hydroxide the monohydrate form is obtained. These two produ
Publikováno v:
ChemInform. 23
The lactones 2a and 2b are different only by the configurationof the carbon C5 of the side-chain, but present quite different features in the ring conformation. Inspection of the NMR spectra of 2b , compared to 2a , shows a evident flattening of the
Publikováno v:
Tetrahedron. 48:1617-1626
The lactones 2a and 2b are different only by the configurationof the carbon C5 of the side-chain, but present quite different features in the ring conformation. Inspection of the NMR spectra of 2b , compared to 2a , shows a evident flattening of the
Publikováno v:
Tetrahedron. 46:5621-5632
The NMR spectra of a series of hindered tetrahydrofuran compounds, disubstituted in C5 and with two polar groups in C2 (Br, Cl or OMe in the anomeric position) and C3 (Br or Cl) have been examined. When the two polar groups are cis, the anomeric grou
Autor:
Gilbert Dana, Estera Touboul
Publikováno v:
Tetrahedron Letters. 31:3549-3552
The stretching frequencies of equatorial and axial fused tetrahydropen C 2 -D bonds appear around 2190 and 2100 cm −1 , with a wide multiplicity. These frequencies are lowered by 20 to 70 cm −1 when an OR group is added on C2. An sp 2 hybridizati
Autor:
Gilbert Dana
Publikováno v:
Caractérisation et propriétés de la matière.
Les methodes spectroscopiques sont des procedes d’etude physique mettant en jeu des phenomenes d’echange d’energie entre la matiere et un rayonnement electromagnetique. Il peut s’agir d’ absorption ou d’ emission de lumiere, la « lumiere
Autor:
Gilbert Dana
Publikováno v:
Caractérisation et propriétés de la matière.
Comme toute methode spectroscopique, la spectroscopie infrarouge met en jeu des echanges d’energie entre une molecule et un rayonnement electromagnetique. Dans l’infrarouge proche (12 500 a 4 000 cm −1 ) et moyen (4 000 a 650 cm −1 ), on obse
Publikováno v:
Tetrahedron. 44:429-442
Resume Les aryl-2- tetrahydrofurannes de la figure 1 ont ete examines par RMN du proton. Les couplages vicinaux montrent clairement qu'a l'interieur mĕme de chacune des series a , b ou c , le tetrahydrofuranne peut subir une inversion conformationne
Publikováno v:
Canadian Journal of Chemistry. 54:1827-1836
The 13C nmr spectra of derivatives of phenylfuran and phenylpyrrole were studied. The α and β carbons of the heterocycle, conjugated to the substituent X in the para position of the benzene ring, show variations in chemical shifts which bear a simp