Zobrazeno 1 - 10
of 27
pro vyhledávání: '"Gianluigi Luppi"'
Publikováno v:
ChemPlusChem. 80:62-67
A simple approach for the functionalization of cylindrically shaped zeolite L crystals with iron oxide magnetic nanoparticles is reported. These functionalized zeolites can be aligned very easily by applying a magnetic field in solution, on different
Autor:
Manuel Tsotsalas, Luisa De Cola, Gianluigi Luppi, Kristina Riehemann, Jürgen Klingauf, Jana Hüve, Christina Krampe, Zhen Li
Publikováno v:
Small
Information about the mechanisms underlying the interactions of nanoparticles with living cells is crucial for their medical application and also provides indications of the putative toxicity of such materials. Here the uptake and intracellular deliv
Autor:
Rodrigo J. Corrêa, Angelo C. Pinto, Gianluigi Luppi, Magda Monari, Quirinus B. Broxterman, Bernard Kaptein, Simon J. Garden, Flávio A. Violante, Claudia Tomasini
Publikováno v:
Tetrahedron. 62:12017-12024
The first total synthesis of (R)-convolutamydine A has been achieved by the organocatalytic addition of acetone to 4,6-dibromoisatin. The absolute configuration was determined by single crystal X-ray diffraction. DFT studies were used to model the tr
Publikováno v:
Tetrahedron: Asymmetry. 15:1645-1650
Novel homo-oligomers of the Gly-L-Oxd moiety have been prepared and their preferential conformations have been analyzed by IR, 1H NMR and CD spectroscopy, with the aim of checking whether these molecules are able to fold in ordered structures. We hav
Publikováno v:
Org. Biomol. Chem.. 2:2181-2187
A total synthesis in solution and a conformational analysis of the homo-oligomers of (4R)-(2-oxo-1,3-oxazolidin-4-yl)-acetic acid (D-Oxac) to the tetramer level are described. As the D-Oxac building block contains both an oxazolidin-2-one and a beta-
Autor:
Gianluigi Luppi, and Andrea Garelli, Claudia Tomasini, Marco Garavelli, Valerio Trigari, Donato Lanci
Publikováno v:
The Journal of Organic Chemistry. 68:1982-1993
The liquid-phase synthesis and the conformational analysis of a small library of fully protected tetramers containing L-pyroglutamic acid (L-pGlu), (45,5R)-4-methyl-5-carboxybenzyloxazolidin-2-one (L-Oxd), or (4R,5S)-4-methyl-5-carboxybenzyloxazolidi
Autor:
Gianluigi Luppi, Claudia Tomasini
Publikováno v:
Synlett. :0797-0800
A straightforward synthesis of enantiomerically pure (4R,5S)-5-oxazolidinecarboxylic acid, 2-oxo-4-[(t-butyldimethylsilyloxy)methyl]-, benzyl ester and of (4S,5S)-4-oxazolidinecarboxylic acid, 2-oxo-5-[(t-butyldimethylsilyloxy)methyl]-, benzyl ester
Publikováno v:
Organic & Biomolecular Chemistry. 1:247-250
A four step synthesis of 4(S)-oxazolidineacetic acid, 2-oxo benzyl ester (D-Oxac-OBn) from L-Asp-OH in 45% overall yield is reported. The formation of by-products is completely avoided, by microwave irradiation and by the use of caesium carbonate as
Publikováno v:
Small
Zeolite L nanocrystals, as inorganic host material containing hydrophobic fluorophore N,N′-bis(2,6-dimethylphenyl)perylene-3,4,9,10-tetracarboxylic diimide in the unidirectional channels, are developed as new labels for biosensor systems. The exter
Autor:
Manuel Tsotsalas, Marilyn P. Law, Gianluigi Luppi, Klaus Kopka, Michael Schäfers, Stefan Wagner, Luisa De Cola
Publikováno v:
ACS nano. 4(1)
A new strategy for the radiolabeling of porous nanocontainers has been developed, and the first experiments in vivo are reported. Our approach consists of the use of nanometer-sized zeolites whose channels have been filled with the positively charged