Highly Rigid, Yet Conformationally Adaptable, Bisporphyrin sp ² -Cage Receptors Afford Outstanding Binding Affinities, Chelate Cooperativities, and Substrate Selectivities.

Autor: Gia AP; Nanostructured Molecular Systems and Materials group, Organic Chemistry Department, Universidad Autónoma de Madrid, Madrid 28049, Spain., de Juan A; Nanostructured Molecular Systems and Materials group, Organic Chemistry Department, Universidad Autónoma de Madrid, Madrid 28049, Spain.; Institute for Advanced Research in Chemical Sciences (IAdChem), Universidad Autónoma de Madrid, Madrid 28049, Spain., Aranda D; Institute of Molecular Science, Universidad de Valencia, Catedrático José Beltrán 2, Paterna 46980, Spain., Guijarro FG; Nanostructured Molecular Systems and Materials group, Organic Chemistry Department, Universidad Autónoma de Madrid, Madrid 28049, Spain., Aragó J; Institute of Molecular Science, Universidad de Valencia, Catedrático José Beltrán 2, Paterna 46980, Spain., Ortí E; Institute of Molecular Science, Universidad de Valencia, Catedrático José Beltrán 2, Paterna 46980, Spain., García-Iglesias M; QUIPRE Department, Nanomedicine-IDIVAL, Universidad de Cantabria, Avd. de Los Castros, 46, Santander 39005, Spain., González-Rodríguez D; Nanostructured Molecular Systems and Materials group, Organic Chemistry Department, Universidad Autónoma de Madrid, Madrid 28049, Spain.; Institute for Advanced Research in Chemical Sciences (IAdChem), Universidad Autónoma de Madrid, Madrid 28049, Spain.

Publikováno v: Journal of the American Chemical Society [J Am Chem Soc] 2024 Dec 19. Date of Electronic Publication: 2024 Dec 19.