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pro vyhledávání: '"Ghasan A. Abdul Hadi"'
Autor:
Ulrike Segerer, Steffen Blaurock, Ghasan A. Abdul Hadi, Reinhard Felsberg, Evamarie Hey-Hawkins
Publikováno v:
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When the transition metal halides Cpx 2ZrCl2, CpxZrCl3, CpxMoCl2(Cpx=C5H5, C5H4Me, C5Me4Et), or CpxMCl4 (Cpx=C5H5, C5H4Me, C5Me4Et, C5Me5; M = Nb, Ta, or Mo) are treated with functionalised phosphorus-based ligands (functional group = P-H; P-SiMe3 or
Autor:
Evamarie Hey-Hwakins, Ghasan A. Abdul Hadi, Svea Jelonek, Katharina M. Fromm, Steffen Blaurock
Publikováno v:
Polyhedron. 16:721-731
The rreaction of [Cp′TaCl 4 ] (Cp′ =C 5 H 4 Me) with KPPh 2 (dioxane) 2 (1 : 1) in diethyl ether at room temperature gave the phosphanido-bridge tantalum(III) complex [Cp′Ta(μ-PPh 2 )(PPh 2 )] 2 ( 1 ) · C 7 H 8 as black crystals. [Cp′TaCl 4