Alpha-stabilization of carbanions: fluorine is more effective than the heavier halogens

Autor: Holger Hermann, Gernot Boche, F. Matthias Bickelhaupt

Publikováno v: Bickelhaupt, F M, Hermann, H L & Boche, G 2006, ' Alpha-stabilization of carbanions: fluorine is more effective than the heavier halogens ', Angewandte Chemie International Edition in English, vol. 45, no. 5, pp. 823-6 . https://doi.org/10.1002/anie.200501633
Angewandte Chemie International Edition in English, 45(5), 823-6. John Wiley and Sons Ltd

Ready steady go! The basicity of the carbanions CH

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f24d2ebfdef499141482559163cda631
https://hdl.handle.net/1871.1/bf8de61f-32dc-4737-8e42-5319ec96fea6

Synthesis, Characterization, and 32P-Postlabeling of N-(Deoxyguanosin)-4-aminobiphenyl 3‘-Phosphate Adducts

Autor: Manfred Wiessler, Gernot Boche, Dieter Albert, Torsten Haack, Heinz H. Schmeiser, Christian Kliem

Publikováno v: Chemical Research in Toxicology. 17:776-784

The (32)P-postlabeling assay is an extremely sensitive technique for detecting carcinogen-DNA adducts. However, for the assignment of DNA adduct structures and the accurate determination of DNA adduct levels by (32)P-postlabeling, authentic adduct st

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::9f25561d7c2ec477338f3297c0976554
https://doi.org/10.1021/tx0342666

Metallophilic Interactions in Closed-Shell Copper(I) Compounds—A Theoretical Study

Autor: Holger Hermann, Peter Schwerdtfeger, Gernot Boche

Publikováno v: Chemistry - A European Journal. 7:5333-5342

Cuprophilic interactions in neutral perpendicular model dimers of the type (CH 3 CuX) 2 (X = OH 2 , NH 3 , SH 2 , PH 3 , N 2 , CO, CS, CNH, CNLi) were analyzed by ab initio quantum-chemical methods. The basis set superposition error for the weakly in

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::4df4c386134a6d741cba01617c7fd6dd
https://doi.org/10.1002/1521-3765(20011217)7:24<5333::aid-chem5333>3.0.co

Me2CuLi*LiCN in Diethyl Ether Prefers a Homodimeric Core Structure [Me2CuLi]2 and Not a Heterodimeric One [Me2CuLi*LiCN]: 1H, 6Li HOE and 1H, 1H NOE Studies by NMR

Autor: Carsten Auel, Ruth M. Gschwind, Xiulan Xie, Pattuparambil R. Rajamohanan, Gernot Boche

Publikováno v: Journal of the American Chemical Society. 123:7299-7304

H-Li distances and (1)H-(1)H dipolar interactions in Me(2)CuLiLiCN and Me(2)CuLi in diethyl ether (Et(2)O), obtained by NMR spectroscopy, were used to gain structural information about the contact ion pair of the salt-containing organocuprate Me(2)Cu

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::4d4d3ac8fce85f254efc3431b7446387
https://doi.org/10.1021/ja004350x

The Relation between Ion Pair Structures and Reactivities of Lithium Cuprates

Autor: Pattuparambil R. Rajamohanan, Carsten Auel, Michael John, Christoph Behrens, Ruth M. Gschwind, Ferdinand Bosold, Klaus Harms, Michael Marsch, Gernot Boche

Publikováno v: Chemistry - A European Journal. 6:3060-3068

From Li+ well-solvating solvents or complex ligands such as THF, [12]crown-4, amines etc., lithium cuprates R2CuLi(.LiX) crystallise in a solvent-separated ion pair (SSIP) structural type (e.g. 10). In contrast, solvents with little donor qualities f

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::3a2d64345d65c9970c824d7b859bbb0d
https://doi.org/10.1002/1521-3765(20000818)6:16<3060::aid-chem3060>3.0.co