Zobrazeno 1 - 10
of 1 018
pro vyhledávání: '"Gernot Frenking"'
Publikováno v:
JACS Au, Vol 1, Iss 5, Pp 623-645 (2021)
Externí odkaz:
https://doaj.org/article/0038d19599504cb694d8a6cec83bf8f2
Autor:
Wenbang Yang, Li Zhang, Dengmengfei Xiao, Rui Feng, Wenqing Wang, Sudip Pan, Yue Zhao, Lili Zhao, Gernot Frenking, Xinping Wang
Publikováno v:
Nature Communications, Vol 11, Iss 1, Pp 1-8 (2020)
Stable diradicals are generally based on two s/p-localized or π-delocalized unpaired electrons (radicals). Here, the authors report a dication diradical that is based on two Se∴Se three-electron σ-bonds.
Externí odkaz:
https://doaj.org/article/41ab4657b2f14d6f93b11f2143f5ac30
Autor:
Qian Wang, Sudip Pan, Shujun Lei, Jiaye Jin, Guohai Deng, Guanjun Wang, Lili Zhao, Mingfei Zhou, Gernot Frenking
Publikováno v:
Nature Communications, Vol 10, Iss 1, Pp 1-8 (2019)
The study of main group complexes remains important to our fundamental understanding of main group element bonding and properties. Here the authors isolate and spectroscopically characterize a series of 8-coordinated alkaline earth metal–dinitrogen
Externí odkaz:
https://doaj.org/article/52518d44f7fc46d8a96d907116f94aea
Publikováno v:
Nature Synthesis. 2:423-429
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::cae018ab7ee7873066c702a9b322d484
https://doi.org/10.1038/s44160-023-00247-0
https://doi.org/10.1038/s44160-023-00247-0
Publikováno v:
Nature Communications, Vol 9, Iss 1, Pp 1-8 (2018)
While chemical bonding between carbon and the d- and p-block elements is relatively well-studied, that between carbon and the f-block elements remains comparatively poorly understood. Here, the authors synthesize a series of uranium−carbone complex
Externí odkaz:
https://doaj.org/article/ce342c125aa2476aa2e0c4da28cca06c
Autor:
Simon J. Bonyhady, David Collis, Nicole Holzmann, Alison J. Edwards, Ross O. Piltz, Gernot Frenking, Andreas Stasch, Cameron Jones
Publikováno v:
Nature Communications, Vol 9, Iss 1, Pp 1-6 (2018)
While polyhedral boron hydride complexes have found application in a number of diverse fields, the isolation of stable aluminium analogues remains highly challenging. Here, Jones and colleagues demonstrate that reduction of an amidinato-aluminum(III)
Externí odkaz:
https://doaj.org/article/012ef1d7039b45faa79e5ab9dccc5d25
Autor:
Sudip Pan, Gernot Frenking
Publikováno v:
Chemical Science. 14:379-383
Metal–ligand bonds in M(cAACDip)2 (M = Be, Mg) are best described with dative bonds between neutral ligands L⇄M⇄L but not with charged species L(−1)→E(+2)←L(−1) as previously stated. The oxidation state of the metals is zero but not +2.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::440326a4d234e208db3ae10f461b5690
https://doi.org/10.1039/d2sc04231b
https://doi.org/10.1039/d2sc04231b
Publikováno v:
Chemical Communications. 59:4024-4027
A low-valent Ga(i) complex, [Ga@Bi10(NbMes)2]3−, with a linear Nb–Ga–Nb fragment was synthesized by the reaction of K5Ga2Bi4 with NbMes2. This unusual Zintl cluster represents the first compound with Nb–Ga and Nb–Bi bonds.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::81941539a3da409c53139c38187578b7
https://doi.org/10.1039/d3cc00631j
https://doi.org/10.1039/d3cc00631j
Autor:
Akachukwu D. Obi, Diane A. Dickie, William Tiznado, Gernot Frenking, Sudip Pan, Robert J. Gilliard
Publikováno v:
Inorganic Chemistry. 61:19452-19462
Bismuth complexes stabilized by carbon-based donor ligands are underserved by their instability, often due to facile ligand dissociation and deleterious protonolysis. Herein, we show that the
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::c08706948e12fd650d81f733e726ccba
https://doi.org/10.1021/acs.inorgchem.2c03337
https://doi.org/10.1021/acs.inorgchem.2c03337
Autor:
Dongmin Wang, Cai Zhai, Yizhen Chen, Yuhao He, Xiao-dan Chen, Shanle Wang, Lili Zhao, Gernot Frenking, Xinping Wang, Gengwen Tan
Publikováno v:
Nature Chemistry. 15:200-205
Carbynes (R-[Formula: see text]), species that bear a monovalent carbon atom with three non-bonding valence electrons, are important intermediates and potentially useful in organic synthetic chemistry. However, free species of the type R-[Formula: se
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::51dff9d3d9bb1ecd3054fda23a03fcfc
https://doi.org/10.1038/s41557-022-01081-1
https://doi.org/10.1038/s41557-022-01081-1