Zobrazeno 1 - 10
of 14
pro vyhledávání: '"Germanium difluoride"'
Publikováno v:
The Journal of Chemical Physics. 101:891-898
Spectra of jet‐cooled germanium difluoride were obtained by the reaction of germanium metal and fluorine in the throat of a heated supersonic jet. Two band systems at 331–305 and 231–224 nm were observed by laser‐induced emission excitation s
Autor:
Christian Styger, M. C. L. Gerry
Publikováno v:
Journal of Molecular Spectroscopy. 158:328-338
Rotational transitions of 28 SiF 2 and four isotopomers of GeF 2 have been investigated using a cavity pulsed microwave Fourier transform spectrometer. Both molecules were prepared in electric discharges, in SiF 4 and GeF 4 , respectively. The high r
Autor:
C. H. Van Dyke
Publikováno v:
Inorganic Reactions and Methods: The Formation of Bonds to Halogens (Part 1), Volume 3
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::5c96f2f41356c62e748f8711f06a51bf
https://doi.org/10.1002/9780470145173.ch282
https://doi.org/10.1002/9780470145173.ch282
Autor:
C. H. Van Dyke
Publikováno v:
Inorganic Reactions and Methods: The Formation of Bonds to Halogens (Part 1), Volume 3
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::15b887879a2c08ab5eb053e73a331a3f
https://doi.org/10.1002/9780470145173.ch287
https://doi.org/10.1002/9780470145173.ch287
Autor:
Tariq Mahmood, Charles B. Lindahl
Publikováno v:
Kirk-Othmer Encyclopedia of Chemical Technology
Germanium forms both a difluoride and a tetrafluoride as well as stable trifluorogermanite and hexafluorogermanite ions. Germanium difluoride is a white solid with mp 110C. It can be prepared by the reduction of GeF4 by metallic Ge and by the reactio
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::9db47756caa045c1a585e25b9b9835c1
https://doi.org/10.1002/0471238961.0705181313010813.a01
https://doi.org/10.1002/0471238961.0705181313010813.a01
Publikováno v:
Chemical Physics Letters. 94:585-588
Valence ionization energies of the transient species GeI2, obtained with He(I) photoelectron (PE) spectroscopy, are presented. The interpretation of the results is aided by Hartree-Fock-Slater calculations in which relativistic effects have been take
Publikováno v:
Canadian Journal of Chemistry, Vol. 52, No 1 (1974) pp. 95-99
Matrix infrared and laser Raman spectra are reported for GeF, and (GeF,), in both N2 and Ar matrices. Raman depolarization measurements for the monomer in N, matrices identify vl at 653 cm-l. Warm-up experiments identify infrared and Raman lines at 6
Publikováno v:
Journal of the Less Common Metals. 24:113-116
Publikováno v:
The Journal of Physical Chemistry. 72:4492-4496
Publikováno v:
The Journal of Chemical Thermodynamics. 2:741-744
The energy of fluorination of germanium difluoride has been measured in a bomb calorimeter. From the combustion results the standard enthalpy of formation ΔH f o (GeF 2 ,c, 298.15 K) was determined to be −(157.4 ± 1.0) kcal mol −1 . †