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pro vyhledávání: '"German Ferrando-Miguel"'
Publikováno v:
New J. Chem.. 29:193-204
The synthesis and characterization of Ru(H)2(ortho-OC6H4E)L2 (L = PiPr3, E = NH, O) show these to be dihydrides with a nonoctahedral structure. The former compound reacts with H2 to give Ru(H)3(OC6H4NH2)L2, which has the ability to hydrogenate tBuHCC
Autor:
Joseph N. Coalter, Odile Eisenstein, Kenneth G. Caulton, Hélène Gérard, German Ferrando-Miguel, John C. Huffman
Publikováno v:
New Journal of Chemistry. 26:687-700
Reaction of [RuHCl(PiPr3)2]2 with THF or dioxolane doubly dehydrogenates the carbon α to the oxygen to yield RuHCl(H2)(PiPr3)2, together with the coordinated cyclic carbene, RuHCl[CO(CH2)2E](PiPr3)2, where E=CH2 or O. In the presence of CH2CHtBu as
Publikováno v:
Inorganic chemistry. 41(24)
Os(H)(3)ClL(2) (L = P(i)Pr(3)) reacts at 20 degrees C with vinyl fluoride in the time of mixing to produce OsHFCl([triple bond]CCH(3))L(2) and H(2). In a competitive reaction, the liberated H(2) converts vinyl fluoride to C(2)H(4) and HF in a reactio