Zobrazeno 1 - 10
of 156
pro vyhledávání: '"Gerhard Kossmehl"'
Publikováno v:
Polymer Bulletin. 51:217-224
Two new thiophene derivatives bearing redox active p-nitrophenyl units were synthesized and electropolymerized to conducting polymers. It is found that not only the structure of monomer, but also the employed polymerization conditions have considerab
Publikováno v:
Macromolecular Chemistry and Physics. 202:2790-2796
The antioxidative activity of the title stabilizers has been studied by the initiated oxidation of cumene as a model reaction. The new model compounds prepared from vernonia oil and the conventional phenolic antioxidant 3-(3,5-di-tert-butyl-4-hydroxy
Autor:
Gunnar Engelmann, Hans-Peter Welzel, Wolf-Dietrich Hunnius, Waldfried Plieth, Gerhard Kossmehl
Publikováno v:
Journal of Solid State Electrochemistry. 5:141-149
Polythiophene films containing ester groups on the surface of electrodes are interesting potential carrier materials for reagents. Methyl thiophene-3-acetate (3) can be copolymerized with 3-methylthiophene (1) and 3-butylthiophene (2) by means of cyc
Publikováno v:
Journal of Solid State Electrochemistry. 5:74-79
The mechanism of the electrosynthesis of poly(3-butylthiophene) (PBuT) was studied by cyclic voltammetry and potential step methods in comparison with polybithienyl. The anodic oxidation polymerization of the 3-butylthiophene underwent two steps: oli
Autor:
Eldar B. Zeinalov, Gerhard Koßmehl
Publikováno v:
Polymer Degradation and Stability. 71:197-202
The antioxidative activity of fullerene C60 has been studied by model reaction of the initiated oxidation of cumene and also in accelerated tests of the mixtures with polystyrene and polydimethylsiloxane rubber. It was established that the initiation
Autor:
Gerhard Kossmehl, Jörg Melsheimer, Hesun Zhu, Guangtao Li, Karl Doblhofer, Waldfried Plieth, Wolf-Dietrich Hunnius, Wolfgang Kautek
Publikováno v:
Polymer. 41:423-432
Three new thiophene derivatives containing different activated ester groups covalently attached to the thiophene ring via a linear undecyl spacer have been synthesized. Electropolymerization of these monomers in acetonitrile led to stable electroacti
Autor:
Siu-Choon Ng, Hardy S. O. Chan, Guangtao Li, Waldfried Plieth, Hesun Zhu, Gerhard Koßmehl, Wolfgang Kautek
Publikováno v:
Macromolecular Chemistry and Physics. 201:21-30
The synthesis and electropolymerization of 3-alkylthiophenes functionalized with a terminal amino group and its protected forms are reported. As expected, due to the strong electronic interference of the amino group, the electropolymerization of the
Autor:
Gerhard Koßmehl
Publikováno v:
Nachrichten aus der Chemie. 57:1090-1092
Erkner, eine Kleinstadt ostlich von Berlin, markiert einen Meilenstein der Chemiegeschichte. Im Jahr 1909 wurde hier das erste vollsynthetische Kunstharz der Welt im industriellen Masstab hergestellt: Bakelit.
Autor:
Gerhard Koßmehl, Fred Hollwedel
Publikováno v:
Macromolecular Chemistry and Physics. 200:2612-2622
The synthesis of some new 4-hydroxy, 4-butyloxy, 4-propionyloxy, and 4-acryloyloxy substituted isochroman-3-ones is described. The influence of the substitution pattern in position 1 and 4 on the CO 2 elimination, which leads to high reactive ortho-q
Publikováno v:
Journal of Solid State Electrochemistry. 3:135-140
Photocurrent and differential capacity measurements have been carried out at polybithienyl (PBT) and poly(3-butylthiophene) (PBuT) films on platinum. The photocurrents are cathodic, similar to inorganic p-type semiconductors. The band gap energy was