Zobrazeno 1 - 7
of 7
pro vyhledávání: '"Gerhard Henig"'
Publikováno v:
Organometallics. 22:744-758
While the dinuclear compounds [(η 6 -mes)Os{κ 1 -OC(O)CF 3 (μ-Cl)] 2 (2) and [(η 6 -mes)Os{κ 1 -OS(O) 2 CF 3 }(μ-Cl)] 2 (3), prepared from [(η 6 -mes)OsCl(η 3 -C3H5)] (1) and CF 3 CO 2 H or CF 3 SO 3 H by elimination of propene, are not suita
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::ad21ab4c1dc1b3e1a26822cbeb492365
https://doi.org/10.1021/om0207109
https://doi.org/10.1021/om0207109
Publikováno v:
Dalton Transactions. :441-448
The dimeric starting materials [Ru(η6-arene)Cl2]2 (arene = mes, C6Me6) react with the functionalized phosphines Pri2PCH2X (X = CH2OMe, CO2Me) to give the mononuclear compounds [Ru(η6-arene)(κP-Pri2PCH2X)Cl2] 3–6 which upon treatment with AgPF6 a
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::28523466694b9d6b9c90e385fa971057
https://doi.org/10.1039/b208891f
https://doi.org/10.1039/b208891f
Autor:
Gerhard Henig, Regine Herbst-Irmer, Helmut Werner, Olaf Gevert, Bettina Windmüller, Christopher Lehmann
Publikováno v:
Organometallics. 18:1185-1195
Mono- and dihydridoosmium(II) compounds with [(mes)Os{iPr2P(CH2)nY}] (mes = mesitylene, 1,3,5-trimethylbenzene; n = 2, Y = NMe2, OMe; n = 3, Y = NMe2) as a molecular unit are prepared from the dichloro derivatives [(mes)OsCl2{iPr2P(CH2)nY}] and magne
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::3f16fa5a477d1201f335a1dd824b3396
https://doi.org/10.1021/om980909e
https://doi.org/10.1021/om980909e
Autor:
Gerhard Henig, Helmut Werner
Publikováno v:
Zeitschrift für Naturforschung B. 53:540-544
The dichloroosmium(II) compound [(mes)OsCl2(L)] (2) with L = tBuP(CH2CO2Me)2 reacts with one or two equivalents of AgPF6 to give the mono- or dicationic complexes 3 and 4 containing the phosphanediyldiester as a bi- or tridentate chelating ligand. Co
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::2bdc5e2ccb4ff417cbaf2aca3afc562f
https://doi.org/10.1515/znb-1998-5-608
https://doi.org/10.1515/znb-1998-5-608
Autor:
Hans Georg von Schnering, Helmut Werner, Norbert Mahr, Gerhard Henig, Ulrich Wecker, Karl Peters
Publikováno v:
Chemische Berichte. 128:1175-1181
The mononuclear dichloroosmium(II) complexes [(mes)-Os(L)Cl2] (2-5) with the phosphanyl ether L = iPr2PCH2-CH2OMe and phosphanyl esters L = IPr2P(CH2)nCO2R as ligands are obtained from [(mes)OsCl2]n and L in almost quantitative yield. While compound
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::cf704c4d0e560d96b3183c4b4f7d405b
https://doi.org/10.1002/cber.19951281207
https://doi.org/10.1002/cber.19951281207
Publikováno v:
Organometallics. 19:4687-4689
Using [(η6-mes)Os(κ1-O2CCF3)(κ2-O2CCF3)] (1) and diaryldiazomethanes as the starting materials, the half-sandwich-type carbeneosmium(II) complexes [(η6-mes)Os(κ1-O2CCF3)2(CR2)] (2a−c; R = p-C6H4X with X = H, Me, Cl) were prepared. The dichloro
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::0e1dcbdeafefc753e3b1faceb3942307
https://doi.org/10.1021/om0007062
https://doi.org/10.1021/om0007062
Autor:
Helmut Werner, Gerhard Henig
Publikováno v:
Chemical Communications. :2349-2350
The phosphinoenolate complex 4, which is prepared stepwise from [(mes)RuCl2]2 1 via the neutral and cationic compounds 2 and 3 as isolated intermediates, rearranges slowly in benzene to the thermodynamically more stable phosphinomethanide isomer 5; t
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::bda96f2e37381d65568e15a49c59eab3
https://doi.org/10.1039/a705821g
https://doi.org/10.1039/a705821g