Zobrazeno 1 - 10
of 61
pro vyhledávání: '"Gerald B. Porter"'
Publikováno v:
Canadian Journal of Chemistry. 81:199-203
The mechanism of formation of muonium atoms from positive muons was studied here through measure- ments of the yield of diamagnetic muon states in dipolar aprotic solvents and for scavenger solutions in hexane and methanol. The results are compared w
Publikováno v:
The Journal of Chemical Physics. 118:3233-3236
Studies of the yields of muonium atoms and diamagnetic-species in hexane in the presence of added scavengers have shown, unequivocally, that muonium is not formed by the “delayed” (microsecond) mechanism proposed recently. Instead, the lifetimes
Publikováno v:
Canadian Journal of Chemistry. 81:175-178
The rates of reaction of muonium atoms with solutes, ionic and organic, were studied in solvents of wildly differing polarities (water, methanol, and hexane) and their rate constants were compared, where possible. In these reactions which are thos
Publikováno v:
The Journal of Physical Chemistry A. 101:4741-4744
Two reactions of muonium atoms close to the diffusion-controlled limit were analyzed as a function of solute size and solvent viscosity. With Cr(NCS)63- as solute in water, the reaction is an electron spin-conversion process, and the observed rate is
Autor:
John M. Stadlbauer, David C. Walker, Krishnan Venkateswaran, Gerald B. Porter, Hugh A. Gillis
Publikováno v:
Canadian Journal of Chemistry. 74:1945-1951
Muonium atoms add to the O atom of the carbonyl group of acetone to give the muonated free radical (CH3)2Ċ-O-Mu when the reaction takes place in water or hydrocarbons, but not when the acetone is localized in micelles. Micelles have no effect on the
Autor:
John M. Stadlbauer, Delano P. Chong, Krishnan Venkateswaran, Mark E. Laing, Jan Klugkist, David C. Walker, Gerald B. Porter
Publikováno v:
Hyperfine Interactions. 87:947-952
Muon resonance studies show that muonium atoms (Mu) in ethanol add selectively to certain C-sites of aromatic compounds containing -Cl and -OH substituents. The sites chosen seem to be those carrying the lowest electron density. This helps to charact
Publikováno v:
Hyperfine Interactions. 87:941-946
A competition was established for the reaction of muonium atoms (Mu) between nitrate ions in water and benzene or styrene solubilized in micelles. The nitrate was 3.3-times more efficient at inhibiting muonated free radical formation with benzene tha
Publikováno v:
Hyperfine Interactions. 87:877-882
The muon level-crossing-resonance technique has been used to resolve major discrepancies that exist in muon-spin-resonance studies (both free-radical formation and muonium decay rates) in the competition between benzene and styrene. The results, obta
Autor:
Mary Vijayarani Barnabas, John M. Stadlbauer, Krishnan Venkateswaran, Zhennan Wu, David C. Walker, Gerald B. Porter
Publikováno v:
Journal of the American Chemical Society. 113:9096-9099
Publikováno v:
Advances in Photochemistry, Volume 9
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::459b97274c97487803c28d37f6450c88
https://doi.org/10.1002/9780470133392.ch2
https://doi.org/10.1002/9780470133392.ch2