Zobrazeno 1 - 10
of 590
pro vyhledávání: '"Gerald, Kehr"'
Autor:
Felix Scheidt, Christian Thiehoff, Gülay Yilmaz, Stephanie Meyer, Constantin G. Daniliuc, Gerald Kehr, Ryan Gilmour
Publikováno v:
Beilstein Journal of Organic Chemistry, Vol 14, Iss 1, Pp 1021-1027 (2018)
Herein, we describe a catalytic fluorooxygenation of readily accessible N-allylcarboxamides via an I(I)/I(III) manifold to generate 2-oxazolines containing a fluoromethyl group. Catalysis is conditional on the oxidation competence of Selectfluor®, w
Externí odkaz:
https://doaj.org/article/8f44c7183a2d4562a88dc1f4f05c2339
Publikováno v:
Chemistry – A European Journal.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::d522660951eece44412c1b16b2e1ca6d
https://doi.org/10.1002/chem.202301044
https://doi.org/10.1002/chem.202301044
Autor:
Qiu Sun, Constantin G. Daniliuc, Xiaoye Yu, Christian Mück-Lichtenfeld, Gerald Kehr, Gerhard Erker
Publikováno v:
Journal of the American Chemical Society. 144:7815-7821
Boroles and borapyramidanes are classical and nonclassical constitutional isomers, respectively. It is here shown that they can indeed be interconverted. Treatment of the bis(alkynyl)B(C
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::32fd4f24de9b26727002d0e6cf71be3f
https://doi.org/10.1021/jacs.2c01727
https://doi.org/10.1021/jacs.2c01727
Autor:
Robert Knitsch, Melanie Brinkkötter, Thomas Wiegand, Gerald Kehr, Gerhard Erker, Michael Ryan Hansen, Hellmut Eckert
Publikováno v:
Molecules, Vol 25, Iss 6, p 1400 (2020)
Modern solid-state NMR techniques offer a wide range of opportunities for the structural characterization of frustrated Lewis pairs (FLPs), their aggregates, and the products of cooperative addition reactions at their two Lewis centers. This informat
Externí odkaz:
https://doaj.org/article/1e0357d5711c4074b2283d09735b71b7
Publikováno v:
Dalton Transactions. 51:7695-7704
The BH compounds IMes(ArF)BH(NTf2) (ArF: C6F5 or FpXyl) were converted to the IMes(ArF)BCH2 boraalkenes in a three step reaction sequence of B-methylation with methyllithium, hydride abstraction and deprotonation.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::b4de0b9d8c6962c883443a41d73b94bf
https://doi.org/10.1039/d2dt01193j
https://doi.org/10.1039/d2dt01193j
Autor:
Chaohuang Chen, Constantin G. Daniliuc, Sina Klabunde, Michael Ryan Hansen, Gerald Kehr, Gerhard Erker
Publikováno v:
Chemical Science. 13:10891-10896
The NHC-stabilized boraalkene reacts with nitrosobenzene to give a [2+2] cycloaddition product plus a pair of persistent borylnitroxide radicals. These are thought to be formed by means of a bora nitroso ene reaction followed by H-atom transfer.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::8d0e509c3158239d83cc98b847ccdfd7
https://doi.org/10.1039/d2sc02485c
https://doi.org/10.1039/d2sc02485c
Publikováno v:
Journal of the American Chemical Society. 143:21312-21320
Deprotonation of [(NHC)(Fmes)B-allyl]
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a441bc1a3737255ee3318e43606e0657
https://doi.org/10.1021/jacs.1c09774
https://doi.org/10.1021/jacs.1c09774
Publikováno v:
Angewandte Chemie. 133:27259-27267
The borane FmesBH2 reacts in a three-component reaction with an isonitrile and a small series of organonitriles to give rare examples of the class of dihydro-1,4,2-diazaborole derivatives. In a related way, annulated BN-indolizine derivatives became
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::df9e05a440afcfa9861761076d649b6e
https://doi.org/10.1002/ange.202111946
https://doi.org/10.1002/ange.202111946
Publikováno v:
Angewandte Chemie. 135
Hydroboration of styrene or vinylcyclohexane with the IMes(C
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::11d8156b59f9913c13b714467055bd70
https://doi.org/10.1002/ange.202214700
https://doi.org/10.1002/ange.202214700
Publikováno v:
Journal of the American Chemical Society. 143:14992-14997
The η2-formyl borane system 3 is readily available by carbonylation of the vicinal P/BH frustrated Lewis pair (FLP) 1. It serves as a frustrated C/B Lewis pair toward carbon dioxide or phenylisocyanate. In the presence of B(C6F5)3, it forms the coup
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::d6345ba16aeef3604dead05249d555c6
https://doi.org/10.1021/jacs.1c07465
https://doi.org/10.1021/jacs.1c07465