Zobrazeno 1 - 10
of 65
pro vyhledávání: '"George C. Fortman"'
Autor:
Shunyan Gu, Diane A. Dickie, Robert J. Nielsen, Kathleen H. Taylor, Junqi Chen, T. Brent Gunnoe, William A. Goddard, George C. Fortman
Publikováno v:
Organometallics. 39:1917-1933
Oxidative addition and reductive elimination reactions are central steps in many catalytic processes, and controlling the energetics of reaction intermediates is key to enabling efficient catalysis. A series of oxidative addition and reductive elimin
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::51c5f8d4cd9dec8904f0856723186c15
https://doi.org/10.1021/acs.organomet.0c00122
https://doi.org/10.1021/acs.organomet.0c00122
Autor:
Xiaochen Cai, Burjor Captain, Anjaneyulu Koppaka, Manuel Temprado, Leonardo F. Serafim, George C. Fortman, Carl D. Hoff, Subhojit Majumdar
Publikováno v:
Inorganic Chemistry. 55:10751-10766
The kinetics of the reaction of Ph3SnH with excess •Cr(CO)3C5Me5 = •Cr, producing HCr and Ph3Sn–Cr, was studied in toluene solution under 2–3 atm CO pressure in the temperature range of 17–43.5 °C. It was found to obey the rate equation d[
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::5a92f24f8b26d68655e033167387449f
https://doi.org/10.1021/acs.inorgchem.6b01978
https://doi.org/10.1021/acs.inorgchem.6b01978
Autor:
Ross Fu, T. Brent Gunnoe, William A. Goddard, George C. Fortman, Robert J. Nielsen, Michael S. Webster-Gardiner
Publikováno v:
Catalysis Science & Technology. 5:96-100
The Rh(I) complexes [(FlDAB)Rh(coe)(TFA)] (1) and [(BOZO)Rh(coe)(TFA)] (2) [FlDAB = N,N-bis-(pentafluorophenyl)-2,3-dimethyl-1,4-diaza-1,3-butadiene, coe = cyclooctene, TFA = trifluoroacetate, BOZO = bis(2-oxazolin-2-yl)] are efficient catalyst precu
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::857f9d172bd3115afbd5ec223087d250
https://doi.org/10.1039/c4cy00972j
https://doi.org/10.1039/c4cy00972j
Publikováno v:
ACS Catalysis. 4:4455-4465
In the search for new organometallic catalysts for low-temperature selective conversion of CH_4 to CH_3OH, we apply quantum mechanical virtual screening to select the optimum combination of ligand and solvent on rhodium to achieve low barriers for CH
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::32e431acf42d47f9fa892f87f727276c
https://doi.org/10.1021/cs5005322
https://doi.org/10.1021/cs5005322
Autor:
Dominik Munz, Michael M. Konnick, George C. Fortman, John T. Groves, T. Brent Gunnoe, Roy A. Periana, Nicholas C. Boaz
Publikováno v:
Journal of the American Chemical Society. 136:8393-8401
We describe an efficient system for the direct partial oxidation of methane, ethane, and propane using iodate salts with catalytic amounts of chloride in protic solvents. In HTFA (TFA = trifluoroacetate),20% methane conversion with85% selectivity for
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::c6175c5fedef6ddf529e9169b9e8684e
https://doi.org/10.1021/ja502657g
https://doi.org/10.1021/ja502657g
Autor:
Jamal Uddin, Michal Sabat, Nikki A. Cochrane, George C. Fortman, William H. Myers, Vijay M. Ramdeen, T. Brent Gunnoe, Mark J. Pouy, Samuel A. Delp, Thomas R. Cundari
Publikováno v:
ACS Catalysis. 2:2182-2193
Intramolecular addition of O–H and N–H bonds across carbon–carbon triple bonds to form 5- or 6-membered rings with exocyclic methylene groups for ether products and exocyclic methyl groups for imine products is catalyzed by (IPr)Cu(Me) (IPr = 1
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::3e398e1d4b2bac0b30b9a6a8cda363e6
https://doi.org/10.1021/cs300544w
https://doi.org/10.1021/cs300544w
Autor:
Carl D. Hoff, Lei Zhu, Burjor Captain, Manuel Temprado, George C. Fortman, Veeranna Yempally, Anjaneyulu Koppaka
Publikováno v:
Inorganic chemistry. 55(1)
The reaction of Pt(COD)2 with one equivalent of tri-tert-butylstannane, Bu(t)3SnH, at room temperature yields Pt(SnBu(t)3)(COD)(H)(3) in quantitative yield. In the presence of excess Bu(t)3SnH, the reaction goes further, yielding the dinuclear bridgi
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::952a4f5c835ecdf466705a9551173910
https://pubmed.ncbi.nlm.nih.gov/26673480
https://pubmed.ncbi.nlm.nih.gov/26673480
Publikováno v:
Organometallics
Two well-defined 16-electron ruthenium hydroxide complexes were prepared and successfully used in the racemization of aromatic and aliphatic secondary alcohols. The intrinsic basicity of these new complexes permits for the exclusion of KOtBu in the r
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::839eb4023e973b90e522cb552bc128f5
https://doi.org/10.1021/om200956r
https://doi.org/10.1021/om200956r
Publikováno v:
Organometallics. 30:5487-5492
A series of coordinatively unsaturated NHC–Ir(III) complexes are examined in terms of their catalytic activity toward the solvolysis of ammonia–borane (AB). Utilization of [Ir(ItBu′)2Cl] (2) and [Ir(ItBu′)2][PF6] (3) at 50 ppm catalyst loadin
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::eb0704dc6b41621e6c9c8f16ccf17f65
https://doi.org/10.1021/om2007437
https://doi.org/10.1021/om2007437
Autor:
Carl D. Hoff, Steven P. Nolan, Catherine S. J. Cazin, Elena V. Rybak-Akimova, George C. Fortman, Rajeev Prabhakar, Xiaochen Cai, Charles R. Lhermitte, Subhojit Majumdar, Manuel Temprado, Alexandra M. Z. Slawin, Taryn D. Palluccio, Burjor Captain, Meaghan E. Germain
Publikováno v:
Journal of the American Chemical Society. 133:1290-1293
The reactivity of a number of two-coordinate [Pd(L)(L')] (L = N-heterocyclic carbene (NHC) and L' = NHC or PR(3)) complexes with O(2) has been examined. Stopped-flow kinetic studies show that O(2) binding to [Pd(IPr)(P(p-tolyl)(3))] to form cis-[Pd(I
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::23d0ba133bc6ebef46c4e80854058fdd
https://doi.org/10.1021/ja1103348
https://doi.org/10.1021/ja1103348