Zobrazeno 1 - 7
of 7
pro vyhledávání: '"George A. Kalfas"'
Autor:
George A. Kalfas, Tuyu Xie
Publikováno v:
Macromolecular Symposia. 324:7-10
Autor:
Robin A. Hutchinson, John R. Richards, Christopher Bruni, Anatoly N. Nikitin, George A. Kalfas, Wei Wang
Publikováno v:
Macromolecular Reaction Engineering. 4:691-706
Butyl acrylate solution polymerization has been studied at 80-170 °C over a range of monomer and initiator levels. A PREDICI model has been developed to describe the experiments, taking into account chain backbiting, β-scission, and addition of mac
Publikováno v:
Process Safety Progress. 28:275-281
Consequences of acrylic resin reactor runaways can be devastating, as it is evident in investigation reports of industrial accidents. Critical in preventing major accidents is the safety screening of any acrylic resin formula to be manufactured in la
Autor:
Christopher Bruni, Robin A. Hutchinson, John R. Richards, Anatoly N. Nikitin, George A. Kalfas
Publikováno v:
Macromolecular Theory and Simulations. 18:247-258
The kinetics of butyl acrylate solution polymerization up to high conversion are studied both experimentally and theoretically. New expressions taking into account both inter- and intramolecular transfer to polymer are derived for polymerization rate
Publikováno v:
Computers & Chemical Engineering. 32:2155-2167
This paper presents an evaluation of systems challenges in free-radical solution homo-polymerization as temperature increases. ‘Classical’ chain-polymerization kinetic models (accounting for initiation, propagation, chain transfer to solvent and
Autor:
George A. Kalfas
Publikováno v:
Polymer Reaction Engineering. 6:41-67
A simplified mechanism for the depolymerization of nylon-66 and nylon-6 mixtures via the ammonolysis route is proposed here. The mechanism includes the amide link breakage and amide end dehydration (nitrilation) reactions, plus the ring addition and
Autor:
Andrew M. Rappe, Masoud Soroush, Thomas Rier, Michael Charles Grady, Sriraj Srinivasan, George A. Kalfas
Publikováno v:
Proceedings of the 2011 American Control Conference.
This paper presents a macroscopic mechanistic mathematical modeling and optimization study of a batch polymerization reactor in which self-initiated free-radical polymerization of n-butyl acrylate at 140 and 160°C takes place. The model is obtained