Zobrazeno 1 - 10
of 85
pro vyhledávání: '"Geneviève Cerveau"'
Publikováno v:
Comptes Rendus. Chimie
Comptes Rendus. Chimie, Académie des sciences (Paris), 2007, 10 (9), pp.795. ⟨10.1016/j.crci.2007.05.002⟩
Comptes Rendus. Chimie, Académie des sciences (Paris), 2007, 10 (9), pp.795. ⟨10.1016/j.crci.2007.05.002⟩
This paper describes a solution route to obtain silicon nanoparticles bearing a large range of surface functionalities. Silicon tetrachloride (SiCl4) was reduced using potassium incorporated in graphite (C8K) in dimethoxyethane (DME). The chloride-ca
Publikováno v:
Chemistry of Materials. 16:3794-3799
Nanostructured hybrid materials prepared by sol−gel hydrolysis−polycondensation of the precursor 1,3-bis(propyltrimethoxysilyl)-1,3-diphenylallene P having a bulky rigid and twisted core with two short flexible arms exhibited a self-organization
Publikováno v:
J. Mater. Chem.. 14:3019-3025
Nanostructured hybrid materials were prepared by sol–gel hydrolysis-polycondensation of 1,3,5-tris(p-triethoxysilylphenyl)benzene PR having a rigid structure and 1,3,5-tris(p-trimethoxysilylpropylphenyl)benzene PF having a planar core connected to
Publikováno v:
Canadian Journal of Chemistry. 81:1213-1222
The synthesis and characterization of stable bis(dihydroxymethylsilyl) derivatives are described. These compounds were obtained as microcrystalline powders by controlled hydrolysis in a biphasic medium (ethyl ether water) of the corresponding bis(
Publikováno v:
J. Mater. Chem.. 13:2885-2889
The catalytic polycondensation of the lamellar organized α,ω-organo-bis-silanetriols, 4,4′-bis(trihydroxysilyl)stilbene 1H and 4,4′-bis(trihydroxysilyl)diphenylbut-1,3-diyne 2H is described. The resulting polysilsesquioxane materials X1H and X2
Publikováno v:
Silicon Chemistry. 1:321-331
A study of the polycondensation reaction of 1,4-bis(trihydroxysilyl)benzene 1H by thermal treatment and by a catalytic route is described. The resulting polysilsesquioxane materials O1.5Si-Ph-SiO1.5have been compared with those obtained by the classi
Publikováno v:
Journal of Materials Chemistry. 12:3021-3026
The effect of drying and ageing conditions on both the degree of polycondensation at silicon and the texture connected with the surface properties (BET, porosity) has been investigated in the case of silica and nanostructured hybrid organic–inorgan
Publikováno v:
Organometallics. 21:1560-1564
Synthesis and characterization of the first stable α,ω-bis(silanetriols) containing phenylene, biphenylene, α,ω-bis(phenylene)vinylene, α,ω-bis(phenylene)ethynylene, and α,ω-bis(phenylene)buta-1,3-...
Publikováno v:
Chemistry of Materials. 13:3373-3388
The organic−inorganic hybrid materials obtained by the sol−gel route constitute a new class of solids prepared directly from a molecular precursor in mild conditions. These materials are better des...
Autor:
Gérard Calleja, Liliane Coche-Guérente, Geneviève Cerveau, Pierre Labbé† and, and Francis Carré
Publikováno v:
Organometallics. 20:4211-4215
The thermal ring-opening polymerization of 1,1‘ferrocenediyldichlorosilane (m1) led to the expected poly(ferrocenyldichlorosilane) (p1) and the new dimer d1. The molecular structure of d1 was estab...