Zobrazeno 1 - 10
of 12
pro vyhledávání: '"Gaya Elpitiya"'
Autor:
Konstantinos D. Vogiatzis, Jacob Townsend, Elizabeth J. Johnson, David Jenkins, Gaya Elpitiya, Markus R. Anneser, Joseph F. DeJesus, Xian B. Powers
Publikováno v:
Angew Chem Int Ed Engl
Three five-coordinate iron(IV) imide complexes have been synthesized and characterized. These novel structures have disparate spin states on the iron as a function of the R-group attached to the imide, with alkyl groups leading to low-spin diamagneti
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::296165b778378baf216bd35117bcc9b5
https://doi.org/10.1002/anie.201903132
https://doi.org/10.1002/anie.201903132
Publikováno v:
Organometallics. 38:981-987
N-heterocyclic carbenes (NHCs), and macrocyclic NHCs in particular, have been applied successfully to the stabilization of high oxidation states on transition metal complexes. This access to high oxidation states has enabled their application in oxid
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::6a83b8a7d668d022a454309d3e156c13
https://doi.org/10.1021/acs.organomet.8b00923
https://doi.org/10.1021/acs.organomet.8b00923
Autor:
Gaya Elpitiya, Richard D. Adams
Publikováno v:
Journal of Organometallic Chemistry. 812:115-122
The compound Ir 3 (CO) 9 (μ 3 -Bi), 1 loses CO when heated and condenses to form the hexairidium compoun Ir 6 (CO) 13 (μ 3 -Bi)(μ 4 -Bi), 2 . Compounds 1 and 2 react with PPh 3 to form the PPh 3 derivatives Ir 3 (CO) 9-n (PPh 3 ) n (μ 3 -Bi), 3
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::0576c644fff5070a3a54db85ff54e442
https://doi.org/10.1016/j.jorganchem.2015.08.001
https://doi.org/10.1016/j.jorganchem.2015.08.001
Autor:
Gaya Elpitiya, Richard D. Adams
Publikováno v:
Polyhedron. 103:131-134
Heavy atom metallaheterocycles are an emerging family of new complexes that exhibit new structures and interesting chemical properties. In this work, the iridium–bismuth heterocyclic complex, [Ir4(CO)10(μ-BiPh2)(μ-H)]2, 1 has been obtained from t
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::f8b1dfd2510ded6db88ddeaa0e759b85
https://doi.org/10.1016/j.poly.2015.08.044
https://doi.org/10.1016/j.poly.2015.08.044
Autor:
Konstantin Khivantsev, Douglas A. Blom, Richard D. Adams, Michael D. Amiridis, Oleg S. Alexeev, Gaya Elpitiya
Publikováno v:
Applied Catalysis A: General. 501:10-16
Ammoxidation of propane to acrylonitrile was examined over a Fe3BiOx/SiO2 sample prepared by thermal decarbonylation of [Et4N][Fe3(CO)10(μ3-Bi)] on the surface of mesoporous silica. Catalytic measurements performed at 500 °C showed that this sample
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::3f7b0e10a3ca605d17c4e4296b33168d
https://doi.org/10.1016/j.apcata.2015.04.025
https://doi.org/10.1016/j.apcata.2015.04.025
Publikováno v:
Inorganic chemistry. 56(22)
Multiple distinct oxidative group transfer reactions to low valent chromium were examined. Six new chromium complexes were prepared from a highly electronically unsaturated Cr(II) square planar complex that was supported by a macrocyclic tetracarbene
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f76f466ee63dc15a9cf2b20decb61284
https://pubmed.ncbi.nlm.nih.gov/29116767
https://pubmed.ncbi.nlm.nih.gov/29116767
Publikováno v:
Organometallics. 32:2416-2426
Reactions of the tetrairidium anion [Ir4(CO)11(Ph)]– (1) with [Cu(NCMe)4][BF4] and Ag[NO3] have yielded the new iridium–copper and iridium–silver complexes Ir4(CO)11(μ-η1-Ph)[μ3-Cu(NCMe)] (2) and [Et4N][{Ir4(CO)11Ph}2(μ4-Ag)] (3), respectiv
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::12bcecc83de9cc983fc962ac2fd0d2eb
https://doi.org/10.1021/om400133w
https://doi.org/10.1021/om400133w
Publikováno v:
Organometallics. 31:7264-7271
The reaction of Ir3(CO)9(μ3-Bi) with Ph3GeH yielded the compound Ir3(CO)6(GePh3)3(μ3-Bi)(μ-H)3 (1). When 1 was heated to reflux in hexane, it was transformed into the compound Ir3(CO)6(μ-GePh2)3(μ3-Bi) (2), which contains three bridging GePh2 li
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::c0fcf12ec18dc5f4461b1bcfa2466c40
https://doi.org/10.1021/om300813t
https://doi.org/10.1021/om300813t
Autor:
Gaya Elpitiya, Richard D. Adams
Publikováno v:
Inorganic chemistry. 54(16)
The reaction of Ir3(CO)9(μ3-Bi) with PhAu(NHC) (1), where NHC = 1,3-bis(2,6-diisopropylphenylimidazol-2-ylidene), has yielded the compound Ir3(CO)8(Ph)(μ3-Bi)[μ-Au(NHC)] (2) by the loss of one CO ligand and the oxidative addition of the Au-C (phen
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::aedac9e1b61ea7a2b811d8d650e0d4b3
https://pubmed.ncbi.nlm.nih.gov/26245383
https://pubmed.ncbi.nlm.nih.gov/26245383
The reaction of Ir3(CO)9(?3-Bi), 1, with BiPh3 has yielded a iridium–bismuth cluster complex Ir5(CO)10(?3-Bi)2(?4-Bi), 2. The first examples of bimetallic iridium–bismuth nanoparticles have been subsequently synthesized from 1 and 2, and these ha
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::dc4277f4260df584672589c2a0e0163e
https://eprints.soton.ac.uk/367164/
https://eprints.soton.ac.uk/367164/
