A synthetic, catalytic and theoretical investigation of an unsymmetrical SCN pincer palladacycle

Autor: Gavin W. Roffe, Sarote Boonseng, Christine B. Baltus, Simon J. Coles, Iain J. Day, Rhiannon N. Jones, Neil J. Press, Mario Ruiz, Graham J. Tizzard, Hazel Cox, John Spencer

Publikováno v: Royal Society Open Science, Vol 3, Iss 4 (2016)

The SCN ligand 2-{3-[(methylsulfanyl)methyl]phenyl}pyridine, 1, has been synthesized starting from an initial Suzuki–Miyaura (SM) coupling between 3-((hydroxymethyl)phenyl)boronic acid and 2-bromopyridine. The C–H activation of 1 with in situ for

Externí odkaz: https://doaj.org/article/8b22492a7ea04ea1a78afacb05642174

Inclusion and release of ant alarm pheromones from metal–organic frameworks

Autor: John Spencer, Christopher Dadswell, Joe Paul-Taylor, Andrew D. Burrows, Claire L. Hobday, Arun Sridhar, Gavin W. Roffe, Harina Amer Hamzah, Daniel Rixson, Huan V. Doan, Charlie Wedd, Tina Düren, William O. H. Hughes

Publikováno v: Amer Hamzah, H, Rixson, D, Paul-Taylor, J, Doan, H V, Dadswell, C, W. Roffe, G, Sridhar, A, L. Hobday, C, Charlie Wedd, C, Düren, T, Hughes, W O H, Spencer, J & Burrows, A D 2020, ' Inclusion and release of ant alarm pheromones from metal–organic frameworks ', Dalton Transactions, no. 30 . https://doi.org/10.1039/D0DT02047H
Amer Hamzah, H, Rixson, D, Paul-Taylor, J, Doan, H V, Dadswell, C, Roffe, G W, Sridhar, A, Hobday, C L, Wedd, C, Düren, T, Hughes, W O H, Spencer, J & Burrows, A D 2020, ' Inclusion and release of ant alarm pheromones from metal-organic frameworks ', Dalton Transactions, vol. 49, no. 30, pp. 10334-10338 . https://doi.org/10.1039/d0dt02047h

Zinc(ii) and zirconium(iv) metal-organic frameworks show uptake and slow release of the ant alarm pheromones 3-octanone and 4-methyl-3-heptanone. Inclusion of N-propyl groups on the MOFs allows for enhanced uptake and release over several months. In

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e0aa7487f2f4765f89e3a581b194293f

Unsymmetrical Pincer Palladacycles Synthesis and Reactivity

Autor: John Spencer, Sarote Boonseng, Gavin W. Roffe, Hazel Cox

Pincer palladacycles are an interesting class of monomeric organopalladium complexes with a Pd–C bond, intramolecularly stabilized by two heteroatom containing groups bound to the metal center. Often due to synthetic accessibility, such pincer comp

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::f5a2bfdbcf5ccf295233721ba639659d
https://doi.org/10.1016/b978-0-12-812931-9.00022-0

ChemInform Abstract: Synthesis of Unsymmetrical NCN′ and PCN Pincer Palladacycles and Their Catalytic Evaluation Compared with a Related SCN Pincer Palladacycle

Autor: Graham J. Tizzard, John Spencer, Hazel Cox, Gavin W. Roffe, Simon J. Coles

Publikováno v: ChemInform. 47

1-(3-(Pyridin-2-yl)phenyl)methanamine derivatives have been synthesized and underwent C–H bond activation to afford unsymmetrical NCN′ pincer palladacycles, which were characterised in the solid state. 2-Pyridinyl-phenol and -benzyl alcohols were

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::7a5f4caf69cc679d113231b015f66c3e
https://doi.org/10.1002/chin.201648020

A synthetic, catalytic and theoretical investigation of an unsymmetrical SCN pincer palladacycle

Autor: Sarote Boonseng, Neil John Press, Christine B. Baltus, Gavin W. Roffe, Simon J. Coles, Mario Ruiz, Rhiannon N. Jones, John Spencer, Hazel Cox, Iain J. Day, Graham J. Tizzard

Publikováno v: Royal Society Open Science, Vol 3, Iss 4 (2016)
Royal Society Open Science
ResearcherID

The SCN ligand 2-{3-[(methylsulfanyl)methyl]phenyl}pyridine, 1, has been synthesized starting from an initial Suzuki–Miyaura (SM) coupling between 3-((hydroxymethyl)phenyl)boronic acid and 2-bromopyridine. The C–H activation of 1 with in situ for

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::261f157cb9c340fd4f561601102277c1
https://eprints.soton.ac.uk/402104/