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pro vyhledávání: '"Garrison E. Beye"'
The putative common precursor to siphonarin B, baconipyrone A, baconipyrone C, and caloundrin B was prepared by an enantioselective total synthesis featuring our thiopyran route to polypropionates strategy. In the presence of imidazole, the precursor
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::a628c362396b5b181d5e40fdaed19e26
https://doi.org/10.1016/b978-0-12-814805-1.00003-x
https://doi.org/10.1016/b978-0-12-814805-1.00003-x
Autor:
Athanasios Karagiannis, Garrison E. Beye, Vishal Jheengut, Fabiola Becerril-Jiménez, Dale E. Ward, H. Martin Gillis
Publikováno v:
Synlett. 2011:508-512
Aldol reactions of racemic enolizable dioxolan-protected α-substituted-β-ketoaldehydes with representative achiral ketones catalyzed by proline or 5-(2-pyrrolidine-2-yl)-1H-tetrazole in wet DMSO proceed with dynamic kinetic resolution (or via DYKAT
Publikováno v:
Organic Letters. 11:1373-1376
(1R,3R,5R,7R,8S,9R,10S)-3,5-Diethyl-8,9,10-trimethyl-2,4,6-trioxatricyclo[3.3.1.1(3,7)]decan-1-ol (II), a model of the trioxaadamantane ring system embedded in caloundrin B, was prepared by isomerization of the thermodynamically unstable (9S)-diaster
Publikováno v:
The Journal of Organic Chemistry. 71:8989-8992
The synthesis of serricornin [(4S,6S,7S)-7-hydroxy-4,6-dimethylnonan-3-one], a sex pheromone produced by the female cigarette beetle (Lasioderma serricorne F.), in seven steps from readily available racemic 1,4-dioxa-8-thiaspiro[4.5]decane-6-carboxal
Autor:
Dale E. Ward, Garrison E. Beye
Publikováno v:
Journal of the American Chemical Society. 132(20)
The hypothesis that siphonariid polypropionates originate from nonenzymatic processes on acyclic biosynthetic precursors was tested by examining the properties of the putative common precursor for the S. zelandica decapropionates siphonarin B, caloun
Autor:
Idralyn Q. Alarcon, Garrison E. Beye, Dale E. Ward, Marcelo Sales, H. Martin Gillis, Vishal Jheengut
Publikováno v:
The Journal of organic chemistry. 72(5)
The aldol reaction of tetrahydro-4H-thiopyranone with 1,4-dioxa-8-thiaspiro[4.5]decane-6-carboxaldehyde (I) gives four possible diastereomeric adducts (II). Aldol reactions of I with each of the diastereomers of II and their corresponding methoxymeth
Autor:
George T. Achonduh, Dale E. Ward, Garrison E. Beye, M. Abdul Rasheed, Vishal Jheengut, H. Martin Gillis
Publikováno v:
Synthesis. 2007:e1-e1
Tetrahydro-4 H-thiopyran-4-one was prepared in >75% yield by treatment of dimethyl 3,3′-thiobispropanoate with NaOMe (generated in situ) in THF solution and decarboxylation of the resulting methyl tetrahydro-4-oxo-2 H-thiopyran-3-carboxylate in ref
Publikováno v:
Organic Letters; Mar2009, Vol. 11 Issue 6, p1373-1376, 4p