Zobrazeno 1 - 10
of 22
pro vyhledávání: '"Gargi, Kundu"'
Publikováno v:
ACS Omega, Vol 5, Iss 40, Pp 25477-25484 (2020)
Externí odkaz:
https://doaj.org/article/6b520e498eb049018869eea0e3ca3fc3
Publikováno v:
Inorganics, Vol 10, Iss 7, p 97 (2022)
In this paper, we have used a saturated five-membered N-Heterocyclic carbene (5SIDipp = 1,3-bis-(2,6-diisopropylphenyl)imidazolin-2-ylidine) for the synthesis of SNHC-haloboranes adducts and their further nucleophilic substitutions to put unusual fun
Externí odkaz:
https://doaj.org/article/9246e163177d4b96b793119ad0a219a9
Publikováno v:
Organometallics. 42:276-282
Publikováno v:
Inorganic Chemistry. 61:12991-12997
The reaction of six-membered saturated NHC [1,3-di(2,6-diisopropylphenyl) tetrahydropyrimidine-2-ylidene; henceforth abbreviated as 6-SIDipp] with PhBCl
Publikováno v:
European Journal of Inorganic Chemistry.
Substitution at sp3 boron of a six-membered NHC·BH3: convenient access to a dihydroxyborenium cation
Publikováno v:
Chemical Communications. 58:3783-3786
6-SIDipp·BH3 (1) was reacted with I2 to give corresponding iodoboranes (2 & 3), which underwent nucleophilic substitution reactions to furnish OTf and ONO2 substituted boranes (4–7). Treatment of Br2/H2O with 1 led to a dihydroxyborenium cation (8
Publikováno v:
Dalton Transactions. 51:14452-14457
While 6-SIDipp cleaves the B–H bond of pinacolborane (HBpin) to afford the desired 1,1-oxidative-addition product (7), it undergoes ring expansion with 9-borabicyclo[3.3.1]nonane (9-BBN), leading to a seven-membered ring (6b).
Publikováno v:
Chemical Science.
Addition of water to a 3c–2e boron gallium hydrido compound results in capturing of the parent oxoborane moiety, B(H)O. The latter reacts with another molecule of water to give a boracarboxylic acid derivative.
Publikováno v:
Inorganics; Volume 10; Issue 7; Pages: 97
In this paper, we have used a saturated five-membered N-Heterocyclic carbene (5SIDipp = 1,3-bis-(2,6-diisopropylphenyl)imidazolin-2-ylidine) for the synthesis of SNHC-haloboranes adducts and their further nucleophilic substitutions to put unusual fun
Publikováno v:
Organometallics. 39:4696-4703
Compounds of boranes with N-heterocyclic carbenes are known, yet little attention has been paid to NHC compounds of boron bearing methyl and halogen moieties together. The reason can be attributed ...