Zobrazeno 1 - 10
of 38
pro vyhledávání: '"Gareth M. Roberts"'
Ultraviolet Absorption Induces Hydrogen‐Atom Transfer in G⋅C Watson–Crick DNA Base Pairs in Solution
Autor:
Katharina Röttger, Hugo J. B. Marroux, Michael P. Grubb, Philip M. Coulter, Hendrik Böhnke, Alexander S. Henderson, M. Carmen Galan, Friedrich Temps, Andrew J. Orr‐Ewing, Gareth M. Roberts
Publikováno v:
Angewandte Chemie. 127:14932-14935
Autor:
Arsène F. M. Chemin, Hugo J. B. Marroux, M. Carmen Galan, Thomas A. A. Oliver, Andrew J. Orr-Ewing, Steven T. G. Street, Gareth M. Roberts, Katharina Röttger, Alexander S. Henderson, Emma Elsdon
Publikováno v:
Roettger, K, Marroux, H, Chemin, A, Elsdon, E, Oliver, T A A, Street, S, Henderson, A S J, Galan, C, Orr-Ewing, A & Roberts, G 2017, ' Is UV-Induced Electron-Driven Proton Transfer Active in a Chemically Modified A•T DNA Base Pair? ', Journal of Physical Chemistry B, vol. 121, no. 17, pp. 4448-4455 . https://doi.org/10.1021/acs.jpcb.7b02679
The Journal of Physical Chemistry B
The Journal of Physical Chemistry B
Transient electronic and vibrational absorption spectroscopies have been used to investigate whether UV-induced electron-driven proton transfer (EDPT) mechanisms are active in a chemically modified adenine-thymine (A·T) DNA base pair. To enhance the
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f224ed8b650f35789d8a24c7db594d4f
https://research-information.bris.ac.uk/en/publications/97f10738-7d1a-4299-aaa0-68498d8f69b3
https://research-information.bris.ac.uk/en/publications/97f10738-7d1a-4299-aaa0-68498d8f69b3
Autor:
Hui Yu, Gareth M. Roberts, Nicholas L. Evans, Adam S. Chatterley, Susanne Ullrich, Vasilios G. Stavros
Publikováno v:
The Journal of Physical Chemistry A. 118:9438-9444
We have investigated the effects of quantum tunneling on the photodissociation dynamics of ammonia, following below and above barrier photoexcitation of low-lying levels of the ν'(2) umbrella mode of the NH(3) Ã state (NH(3) (Ã)). This barrier sep
Autor:
Adam S. Chatterley, Michael Staniforth, Vasilios G. Stavros, Gareth M. Roberts, Jamie D. Young
Publikováno v:
Biomedical Spectroscopy and Imaging. 3:271-279
Autor:
Gareth M. Roberts, Vasilios G. Stavros, David J. Hadden, Tolga N. V. Karsili, Stephanie J. Harris, Martin J. Paterson, L. Therese Bergendahl, Michael N. R. Ashfold, Andreas M. Wenge
Publikováno v:
Roberts, G M, Hadden, D J, Bergendahl, L T, Wenge, A M, Harris, S J, Karsili, T N V, Ashfold, M N R, Paterson, M J & Stavros, V G 2013, ' Exploring quantum phenomena and vibrational control in σ* mediated photochemistry ', Chemical Science, vol. 4, no. 3, pp. 993-1001 . https://doi.org/10.1039/c2sc21865h
Non-adiabatic dynamics involving 1πσ* or 1nσ* excited electronic states play a key role in the photochemistry of numerous heteroatom containing aromatic (bio-)molecules. In this contribution, we investigate more exotic phenomena involved in σ* me
Autor:
Angus T. Voice, Hendrik Böhnke, Hugo J. B. Marroux, Gareth M. Roberts, David Morris, Friedrich Temps, Andrew J. Orr-Ewing, Katharina Röttger
Publikováno v:
Roettger, K, Marroux, H J B, Böhnke, H, Morris, D T J, Voice, A, Temps, F, Roberts, G M & Orr-Ewing, A J 2016, ' Probing the excited state relaxation dynamics of pyrimidine nucleosides in chloroform solution ', Faraday Discussions, vol. 2016, no. 194, pp. 683-708 . https://doi.org/10.1039/C6FD00068A
Ultrafast transient electronic and vibrational absorption spectroscopy (TEAS and TVAS) of 2′-deoxy-cytidine (dC) and 2′-deoxy-thymidine (dT) dissolved in chloroform examines their excited-state dynamics and the recovery of ground electronic state
Publikováno v:
The Journal of Physical Chemistry Letters. 3:348-352
The excited-state dynamics of phenol following ultraviolet (UV) irradiation have received considerable interest in recent years, most notably because they can provide a model for understanding the UV-induced dynamics of the aromatic amino acid tyrosi
Autor:
Susanne Ullrich, Gareth M. Roberts, Nicholas L. Evans, Hui Yu, Vasilios G. Stavros, Craig A. Williams
Publikováno v:
The Journal of Physical Chemistry A. 116:2600-2609
The role of ultraviolet photoresistance in many biomolecules (e.g., DNA bases and amino acids) has been extensively researched in recent years. This behavior has largely been attributed to the participation of dissociative (1)πσ* states localized a
Dynamics of H-loss in adenine via the 1πσ∗ state using a combination of ns and fs laser spectroscopy
Publikováno v:
Chemical Physics Letters. 446:20-24
One of the key questions underlying adenine’s photochemistry following 266 nm excitation is whether or not the dissociative 1 πσ ∗ state plays an active role in the ensuing dynamics. This work describes how laser fluence studies on the Ad + and
Autor:
Vasilios G. Stavros, Jacob C. Dean, Michael N. R. Ashfold, Michael Staniforth, Tolga N. V. Karsili, Jamie D. Young, Timothy S. Zwier, Federico Mazzoni, Gareth M. Roberts
Publikováno v:
Young, J D, Staniforth, M, Dean, J C, Roberts, G M, Mazzoni, F, Karsili, T N V, Ashfold, M N R, Zwier, T S & Stavros, V G 2014, ' Towards Understanding Photodegradation Pathways in Lignins : The Role of Intramolecular Hydrogen Bonding in Excited States ', Journal of Physical Chemistry Letters, vol. 5, no. 12, pp. 2138-2143 . https://doi.org/10.1021/jz500895w
The photoinduced dynamics of the lignin building blocks syringol, guaiacol, and phenol were studied using time-resolved ion yield spectroscopy and velocity map ion imaging. Following irradiation of syringol and guaiacol with a broad-band femtosecond