Zobrazeno 1 - 10
of 21
pro vyhledávání: '"Gabriel J. Reyes-Rodríguez"'
Autor:
Nomaan M. Rezayee, Gabriel J. Reyes-Rodríguez, Johannes N. Lamhauge, Kendall N. Houk, Chenxi Lu, Sif T. Linde, Karl Anker Jørgensen, Valdemar J. Enemærke
Publikováno v:
Rezayee, N M, Enemærke, V J, Linde, S T, Lamhauge, J N, Reyes-Rodríguez, G J, Jørgensen, K A, Lu, C & Houk, K N 2021, ' An Asymmetric S N 2 Dynamic Kinetic Resolution ', Journal of the American Chemical Society, vol. 143, no. 19, pp. 7509-7520 . https://doi.org/10.1021/jacs.1c02193
The SN2 reaction exhibits the classic Walden inversion, indicative of the stereospecific backside attack of the nucleophile on the stereogenic center. Observation of the inversion of the stereocenter provides evidence for an SN2-type displacement. Ho
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::de56545caa73ef1a2a644ac7fe9c3867
https://doi.org/10.1021/jacs.1c02193
https://doi.org/10.1021/jacs.1c02193
Publikováno v:
Reyes-Rodríguez, G J, Rezayee, N M, Vidal-Albalat, A & Jørgensen, K A 2019, ' Prevalence of Diarylprolinol Silyl Ethers as Catalysts in Total Synthesis and Patents ', Chemical Reviews, vol. 119, no. 6, pp. 4221-4260 . https://doi.org/10.1021/acs.chemrev.8b00583
Diarylprolinol silyl ethers are among the most utilized stereoselective organocatalysts for the construction of complex molecules. With their debut in 2005, these catalysts have been applied in numerous method developments primarily leveraging enamin
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::287a13271f0a9d70609714c243366bc5
https://doi.org/10.1021/acs.chemrev.8b00583
https://doi.org/10.1021/acs.chemrev.8b00583
Autor:
Nomaan M, Rezayee, Valdemar J, Enemærke, Sif T, Linde, Johannes N, Lamhauge, Gabriel J, Reyes-Rodríguez, Karl Anker, Jørgensen, Chenxi, Lu, K N, Houk
Publikováno v:
Journal of the American Chemical Society. 143(19)
The S
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=pmid________::614702442c366f01dee33207f58fe1d8
https://pubmed.ncbi.nlm.nih.gov/33944572
https://pubmed.ncbi.nlm.nih.gov/33944572
Autor:
Gabriel J. Reyes-Rodríguez, Line Næsborg, Teresa A. Palazzo, Karl Anker Jørgensen, Lars A. Leth, Vasco Corti
Publikováno v:
Næsborg, L, Leth, L, Reyes Rodriguez, G J, Palazzo, T A & Jørgensen, K A 2018, ' Direct Enantio- and Diastereoselective Oxidative Homo-Coupling of Aldehydes ', Chemistry: A European Journal, vol. 24, no. 55, pp. 14844-14848 . https://doi.org/10.1002/chem.201803506
A novel strategy for the direct enantioselective oxidative homocoupling of α-branched aldehydes is presented. The methodology employs open-shell intermediates for the construction of chiral 1,4-dialdehydes by forming a carbon–carbon bond connectin
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::c82e7d8cc6cc837f651c23e1e6e7dedc
https://doi.org/10.1002/chem.201803506
https://doi.org/10.1002/chem.201803506
Autor:
Matilde Rusbjerg, Jakob Blom, Casper L. Barløse, Karl Anker Jørgensen, Henriette N. Tobiesen, Marc V. Iversen, Niels Hammer, Gabriel J. Reyes-Rodríguez, Johannes N. Lamhauge
Publikováno v:
Blom, J, Reyes Rodriguez, G J, Tobiesen, H N, Lamhauge, J N, Iversen, M V, Barløse, C L, Hammer, N, Rusbjerg, M & Jørgensen, K A 2019, ' Umpolung Strategy for α-Functionalization of Aldehydes for the Addition of Thiols and other Nucleophiles ', Angewandte Chemie-International Edition, vol. 58, no. 49, pp. 17856-17862 . https://doi.org/10.1002/anie.201911793
Nucleophile–nucleophile coupling is a challenging transformation in organic chemistry. Herein we present a novel umpolung strategy for α-functionalization of aldehydes with nucleophiles. The strategy uses organocatalytic enamine activation and qui
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::6637934f6e9d01618a42daf47b29a1e2
https://pure.au.dk/portal/da/publications/umpolung-strategy-for-functionalization-of-aldehydes-for-the-addition-of-thiols-and-other-nucleophiles(392d5730-182a-4517-8029-cd1380085d7f).html
https://pure.au.dk/portal/da/publications/umpolung-strategy-for-functionalization-of-aldehydes-for-the-addition-of-thiols-and-other-nucleophiles(392d5730-182a-4517-8029-cd1380085d7f).html
Autor:
Lars A. Leth, Gabriel J. Reyes-Rodríguez, Henriette N. Tobiesen, Line Næsborg, Marc V. Iversen, Karl Anker Jørgensen
Publikováno v:
Leth, L A, Næsborg, L, Reyes-Rodríguez, G J, Tobiesen, H N, Iversen, M V & Jørgensen, K A 2018, ' Enantioselective Oxidative Coupling of Carboxylic Acids to α-Branched Aldehydes ', Journal of the American Chemical Society, vol. 140, no. 40, pp. 12687-12690 . https://doi.org/10.1021/jacs.8b07394
A new reactivity in organocatalysis is proposed to account for the coupling of carboxylic acids to α-branched aldehydes by combining primary amine catalysis and an oxidant. The developed methodology is an enantioselective α-coupling of aromatic and
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::5cf2b1f0954ac26edbb8762ffdfc3ad9
https://pure.au.dk/portal/da/publications/enantioselective-oxidative-coupling-of-carboxylic-acids-to-branched-aldehydes(d8d0d027-ad3a-454f-8f4a-7886a5f906bc).html
https://pure.au.dk/portal/da/publications/enantioselective-oxidative-coupling-of-carboxylic-acids-to-branched-aldehydes(d8d0d027-ad3a-454f-8f4a-7886a5f906bc).html
Publikováno v:
Journal of the American Chemical Society. 136:15263-15269
An aryl anion is produced by rapid addition of iodide to the p-benzyne diradical formed by cycloaromatization of an enediyne. The aryl anion is then hydronated (protonated or deuteronated) to form 1-iodotetrahydronaphthalene. Hydrons can be incorpora
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e0368681e7cb993d75c2db918fb5951e
https://doi.org/10.1021/ja507517g
https://doi.org/10.1021/ja507517g
Publikováno v:
Journal of Physical Organic Chemistry. 26:206-210
Enediynes undergo cycloaromatization to p-benzyne diradicals. A new reaction of p-benzynes is here presented. Instead of their usual radical reactivity, they add nucleophiles, followed by protonation. Kinetic evidence showed that the rate-limiting st
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::369f2b42c8364a69cd2f116ff861111f
https://doi.org/10.1002/poc.2994
https://doi.org/10.1002/poc.2994
Publikováno v:
Atmospheric Environment. 43:4171-4177
Chemical characterization to determine the organic and nitrogen fractions was performed on cloud water samples collected in a mountaintop site in Puerto Rico. Cloud water samples showed average concentrations of 1.09 mg L−1 of total organic carbon
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::b60a0c6446ece3d4724b9f12ad91ae2f
https://doi.org/10.1016/j.atmosenv.2009.05.049
https://doi.org/10.1016/j.atmosenv.2009.05.049
Autor:
Adriana Gioda, Gilmarie Santos-Figueroa, Gabriel J. Reyes-Rodríguez, Jeffrey L. Collett, Olga L. Mayol-Bracero
Publikováno v:
Journal of Atmospheric Chemistry. 61:85-99
Chemical characterization was performed on cloud and rainwater samples collected as part of the Rain In Cumulus over the Ocean Experiment (RICO). This experiment took place at a mountaintop site (East Peak) in Puerto Rico from December 2004 to March
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::2e20f34972d2058f3aff20cff695bf6b
https://doi.org/10.1007/s10874-009-9125-6
https://doi.org/10.1007/s10874-009-9125-6