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Publikováno v:
Macromolecules, 49(3), 796-806. American Chemical Society
Macromolecules, 49(3), 796-806. AMER CHEMICAL SOC
Macromolecules, 49(3), 796-806. AMER CHEMICAL SOC
A kinetic analysis on the aluminum salen-catalyzed ring-opening polymerization (ROP) of (macro)lactones is presented, which focuses on how chain transfer agents and the steric hindrance at the alpha-methylene groups of both the growing chain and the